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Principles of Instrumental Analysis

7th Edition

ISBN:9781305577213

Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Chapter7: Components Of Optical Instruments

Section: Chapter Questions

Problem 7.16QAP

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Question

The IR spectrum of compound A with a molecular formula of C₅H₁₂O is shown below. Compound A is oxidized to give compound B, a ketone with a molecular formula of C₅H₁₀O. When compound A is heated with H₂SO₄, compounds C and D are obtained. Considerably more D is obtained than C.
Reaction of compound C with O₃, followed by treatment with dimethyl sulfide, gives two products: formaldehyde and compound E, with a molecular formula of C₄H₈O. Reaction of compound D with O₃, followed by treatment with dimethyl sulfide, gives two products: compound F, with a molecular formula of C₃H₆O, and compound G, with a molecular formula of C₂H₄O. What are the structures of compounds A through G?

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Wavenumber (cm

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

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