Answered: 5) C,H,X in this compound MASS SPECTRUM…

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter14: Mass Spectrometry

Section: Chapter Questions

Problem 14.27P: Following is the mass spectrum of an unknown compound. The two highest peaks are at m/z 120 and 122....

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FOR EACH SPECTRUM BELOW, • IDENTIFY (ASSIGN) THE MOLECULAR ION PEAK AND THE MOLECULAR WT OF THE COMPOUND. ( KEEP IN MIND THAT SOMETIMES THE MOLECULAR ION MAY NOT BE PRESENT, ESPECIALLY FOR LARGE AND BRANCHED CHAIN MOLECULES WITH NO RINGS SINCE THEY CAN FORM STABLE CATION FRAGMENTS) • IDENTIFY THE BASE PEAK AND DRAW STRUCTURE FOR IT ( ASSIGNING THE PEAKS).) • ASSIGN STRUCTURES FOR OTHER PROMINENT FRAGMENTS IF POSSIBLE • BASED ON THIS, SUGGEST A STRUCTURE FOR THE COMPOUND THAT IS CONSISTENT WITH THE DEGREE OF UNSATURATION OF THE COMPOUND INDICATE THE BONDS THAT FRAGMENT, RESULTING IN THE OBSERVED MASS SPECTRAL FRAGMENTS

5) C,H,X in this compound
100
80
60
40
20-
MASS SPECTRUM
0.0
20
40
60
80
100
m/z
NIST Chemistry WebBook (https://webbook.nist.gov/chemistry)
Rel. Intensity
120

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