( do 5 with explanation 5. A compound having molecular formula CSHẠOS reacts with hydrazine hydrate forming aproduct C with molecular formula C10H&N2S2. The 'H-NMR and 13C-NMR spectra of the productis given below. Identify compounds A and C. Also, assign each NMR peak.TDA.esp1.0-0.9-0.8-0.7-E 0.69 0.50.4-0.30.20.1-160150 14011070Chemical Shift (ppm)1301201009080605040302010TDA.esp1.0-0.9-0.8-0.7-0.6-'H-NMR (500 MHz, CDC33 at 300K) 8: 8.80 (s), 7.500.5-(d), 7.44 (d), 7.296 (s, CDCI3) 7.14 (m).0.4-13C-NMR (500 MHz, CDC13 at 300K) 8: 155.80 (s),0.3-139.02 (s), 132.42 (s), 130.05 (s), 127.84 (s), 76.80 (t, CDCI3).0.2-0.1-1086.Chemical Shift (ppm)ETDA.esp0.55-0.50-0.45-0.40-0.35-0.30-0.25-0.20-0.150.10-0.05-7.35Chemical Shift (ppm)7.507.457.407.307.257.207.15Fig= Aromatic part expandedNormalized IntensityNormalized IntensityNormalized Intensity-7.50

Answered: Image /qna-images/answer/51c45c0b-70f3-42b7-96cd-fb384cc2cbc9.jpg

5. A compound having molecular formula CSHẠOS reacts with hydrazine hydrate forming a product C with molecular formula C10H&N2S2. The 'H-NMR and 1³C-NMR spectra of the product is given below. Identify compounds A and C. Also, assign each NMR peak. TDA.esp 1.0- 0.9 0.8- 0.7- 0.6 10.5 0.4 0.3- 0.2 0.1- 160 150 140 130 120 110 100 90 80 70 60 50 30 20 10 Chemical Shift (ppm) ITDA.esp 1.0국 0.9- 0.8 0.7- 0.6- 0.5 'H-NMR (500 MHz, CDCl3 at 300K) 8: 8.80 (s), 7.50 (d), 7.44 (d), 7.296 (s, CDCI3) 7.14 (m). 0.4- 13C-NMR (500 MHz, CDC3 at 300K) 8: 155.80 (s), 0.3 139.02 (s), 132.42 (s), 130.05 (s), 127.84 (s), 76.80 (t, CDCI3). 0.2- 0.1 10 9 2 Chemical Shift (ppm) TDA.esp 0.55- 0.50- 0.45- 0.40- 0.35 0.30- 0.25. 0.20 0.15 0.10 0.05 7.50 7.45 7.30 7.15 7.35 Chemical Shift (ppm) 7.40 7.25 7.20 Normalized Intensity Normalized Intensity Normaliad Intensity 139.02

5. A compound having molecular formula CSHẠOS reacts with hydrazine hydrate forming a product C with molecular formula C10H&N2S2. The 'H-NMR and 1³C-NMR spectra of the product is given below. Identify compounds A and C. Also, assign each NMR peak. TDA.esp 1.0- 0.9 0.8- 0.7- 0.6 10.5 0.4 0.3- 0.2 0.1- 160 150 140 130 120 110 100 90 80 70 60 50 30 20 10 Chemical Shift (ppm) ITDA.esp 1.0국 0.9- 0.8 0.7- 0.6- 0.5 'H-NMR (500 MHz, CDCl3 at 300K) 8: 8.80 (s), 7.50 (d), 7.44 (d), 7.296 (s, CDCI3) 7.14 (m). 0.4- 13C-NMR (500 MHz, CDC3 at 300K) 8: 155.80 (s), 0.3 139.02 (s), 132.42 (s), 130.05 (s), 127.84 (s), 76.80 (t, CDCI3). 0.2- 0.1 10 9 2 Chemical Shift (ppm) TDA.esp 0.55- 0.50- 0.45- 0.40- 0.35 0.30- 0.25. 0.20 0.15 0.10 0.05 7.50 7.45 7.30 7.15 7.35 Chemical Shift (ppm) 7.40 7.25 7.20 Normalized Intensity Normalized Intensity Normaliad Intensity 139.02

EBK A SMALL SCALE APPROACH TO ORGANIC L

4th Edition

ISBN:9781305446021

Author:Lampman

Publisher:Lampman

Chapter61: Friedel–crafts Acylation

Section: Chapter Questions

Problem 8Q

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