5. Gasoline is composed primarily of hydrocarbons, including many with eight carbon atoms, called octanes. One of the deanest-buming octanes is a compound called 2,3,4- trimethylpentane, which has the following structural formula: CH, CH, CH, HC-CH-CH-CH-CH, The complete combustion of one mole of this compound to COng and H,O leads to AH = -5064.9 k). a. Write a balanced equation for the combustion of 1 mol of CaHran. b. By using the information in this problem and data in the thermodynamic properties table, calculate AH; for 2,3,4-trimethylpentane.

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8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
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Chapter8: Thermochemistry
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Answer Question number 5 (a and b)

4Gılll Gilll
00:21
* 67%
f [Template] Mo... /
Answer the following problems:
1. Two solid objects, A and B, are placed in boiling water and allowed to come to
the temperature of the water. Each is then lifted out and placed in separate
beakers containing 1000 g of water at 10.0 °C. Object A increases the water
temperature by 3.50 °C; B increases the water temperature by 2.60 C.
a. Which object has the larger heat capacity?
b. What can you say about the specific heats of A and B?
2. The specific heat of octane, CsHss0), is 2.22 Jig-K.
a. How many J of heat are needed to raise the temperature of 80.0 g of
octane from 10.0 to 25.0 °C?
b. Which will require more heat, increasing the temperature of 1 mol of
CH18, by a certain amount or increasing the temperature of 1 mol of
HOm by the same amount?
3. Calculate the enthalpy change for the reaction
P.0a (4) + 2 02 (0) - P,010(5)
given the following enthalpies of reaction:
AH = -1640.1 k)
Pa (s) + 302 (9) - P,0.4)
Pa (s) + 5 02 (9) - P,010 (9)
AH = -2940.1 k)
4. From the enthalpies of reaction
H2 (9) + F2 (0) - 2 HF)
C9 +2 F2 (0) - CF. (6)
2 C) +2 H2 (0) - CHa (0)
AH = -537 k)
AH = -680 k/
AH = +52.3 k)
calculate AH for the reaction of ethylene with F2:
12
THERMOCHEMISTRY
...
CH4 (9) + 6 F2 (9) + 2 CF, () + 4 HF)
5. Gasoline is composed primarily of hydrocarbons, including many with eight
carbon atoms, called octanes. One of the deanest-buming octanes is a
compound called 2,3,4- trimethylpentane, which has the following structural
formula:
сн, сн, сн,
H;C-CH-CH-CH-CH,
The complete combustion of one mole of this compound to COzig and H2Og
leads to AH° = -5064.9 k).
a. Write a balanced equation for the combustion of 1 mol of CaH18n.
b. By using the information in this problem and data in the thermodynamic
properties table, calculate AH for 2,3,4-trimethylpentane.
6. The following is known as the thermite reaction:
2 Alg + Fe,0s(4) - Al,03(9) + 2 Feg)
This highly exothermic reaction is used for welding massive units, such as propellers for
large ships. Using standard enthalpies of formation, calculate AH° for this reaction.
I hope you'll enjoy the task
Answer Key
Transcribed Image Text:4Gılll Gilll 00:21 * 67% f [Template] Mo... / Answer the following problems: 1. Two solid objects, A and B, are placed in boiling water and allowed to come to the temperature of the water. Each is then lifted out and placed in separate beakers containing 1000 g of water at 10.0 °C. Object A increases the water temperature by 3.50 °C; B increases the water temperature by 2.60 C. a. Which object has the larger heat capacity? b. What can you say about the specific heats of A and B? 2. The specific heat of octane, CsHss0), is 2.22 Jig-K. a. How many J of heat are needed to raise the temperature of 80.0 g of octane from 10.0 to 25.0 °C? b. Which will require more heat, increasing the temperature of 1 mol of CH18, by a certain amount or increasing the temperature of 1 mol of HOm by the same amount? 3. Calculate the enthalpy change for the reaction P.0a (4) + 2 02 (0) - P,010(5) given the following enthalpies of reaction: AH = -1640.1 k) Pa (s) + 302 (9) - P,0.4) Pa (s) + 5 02 (9) - P,010 (9) AH = -2940.1 k) 4. From the enthalpies of reaction H2 (9) + F2 (0) - 2 HF) C9 +2 F2 (0) - CF. (6) 2 C) +2 H2 (0) - CHa (0) AH = -537 k) AH = -680 k/ AH = +52.3 k) calculate AH for the reaction of ethylene with F2: 12 THERMOCHEMISTRY ... CH4 (9) + 6 F2 (9) + 2 CF, () + 4 HF) 5. Gasoline is composed primarily of hydrocarbons, including many with eight carbon atoms, called octanes. One of the deanest-buming octanes is a compound called 2,3,4- trimethylpentane, which has the following structural formula: сн, сн, сн, H;C-CH-CH-CH-CH, The complete combustion of one mole of this compound to COzig and H2Og leads to AH° = -5064.9 k). a. Write a balanced equation for the combustion of 1 mol of CaH18n. b. By using the information in this problem and data in the thermodynamic properties table, calculate AH for 2,3,4-trimethylpentane. 6. The following is known as the thermite reaction: 2 Alg + Fe,0s(4) - Al,03(9) + 2 Feg) This highly exothermic reaction is used for welding massive units, such as propellers for large ships. Using standard enthalpies of formation, calculate AH° for this reaction. I hope you'll enjoy the task Answer Key
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