5. Molar concentration of iron salicylate ion in 50 mL volumetric flask (calculated using equation of line) 6. Molar concentration of iron salicylate ion in 250 mL volumetric flask (parent aspirin stock solution) 7. Moles of iron salicylate ion in 250 mL volumetric flask (parent aspirin stock solution)

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
ChapterA1: Evaluation Of Analytical Data
Section: Chapter Questions
Problem A1.22QAP
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The molar mass of acetylsalicylic acid is 180.16 g mol 1
Part A: Mass of acetylsalicylic acid data and molar concentration calculation
Unrounded
Rounded
Unit
Mass of acetylsalicylic acid in 1 L
1.5739
g
solution
1. Molar concentration of acetylsalicylic
0.00876310
0.00876
mol L-1
acid
Part A: Volume data, ferric salicylate ion concentration calculation and absorbance data
Trial
Volume of solution
Final volume
2. [Fe-salicylate ion] (mol L¯!)
Absorbance
S (mL)
(mL)
Unrounded
Rounded
Blank (
FeCl3
soln used
0.00
50.00
0.00000
0.00
0.000
to calibrate
colorimeter)
1
2.00
50.00
3.50500 x 104
3.51 x 104
0.261
3.00
50.00
5.25700 x 104
5.26 x 10-4
0.376
3
4.00
50.00
7.01000 x 104
7.01 x 104
0.523
5.00
50.00
8.76300 x 104
8.76 x 104
0.656
6.00
50.00
0.00105150
1.05 x 103
0.778
Part A: Slope and intercept calculation
Unrounded
Rounded
Unit
3. Slope
749.750
7.50 × 102
L mol-
-0.00241872
4. y-intercept
6.80000× 103
-0.00242
Unitless
Transcribed Image Text:The molar mass of acetylsalicylic acid is 180.16 g mol 1 Part A: Mass of acetylsalicylic acid data and molar concentration calculation Unrounded Rounded Unit Mass of acetylsalicylic acid in 1 L 1.5739 g solution 1. Molar concentration of acetylsalicylic 0.00876310 0.00876 mol L-1 acid Part A: Volume data, ferric salicylate ion concentration calculation and absorbance data Trial Volume of solution Final volume 2. [Fe-salicylate ion] (mol L¯!) Absorbance S (mL) (mL) Unrounded Rounded Blank ( FeCl3 soln used 0.00 50.00 0.00000 0.00 0.000 to calibrate colorimeter) 1 2.00 50.00 3.50500 x 104 3.51 x 104 0.261 3.00 50.00 5.25700 x 104 5.26 x 10-4 0.376 3 4.00 50.00 7.01000 x 104 7.01 x 104 0.523 5.00 50.00 8.76300 x 104 8.76 x 104 0.656 6.00 50.00 0.00105150 1.05 x 103 0.778 Part A: Slope and intercept calculation Unrounded Rounded Unit 3. Slope 749.750 7.50 × 102 L mol- -0.00241872 4. y-intercept 6.80000× 103 -0.00242 Unitless
Strength of aspirin tablet (mg acetylsalicylic acid)
500
mg
Absorbance of aspirin solution
0.191
Unitless
ASPIRIN TABLET CALCULATIONS
Part B: Calculations
Unrounded
Rounded
Units
5. Molar concentration of iron salicylate ion in 50 mL
volumetric flask (calculated using equation of line)
A
4
mol L
6. Molar concentration of iron salicylate ion in 250 mL
volumetric flask (parent aspirin stock solution)
6.
4
mol L-1
7. Moles of iron salicylate ion in 250 mL volumetric flask
mol
(parent aspirin stock solution)
8. Calculated mass of acetylsalicylic acid in the tablet
6.
mg
9. Percent error in mass of acetylsalicylic acid in the
%
tablet
Transcribed Image Text:Strength of aspirin tablet (mg acetylsalicylic acid) 500 mg Absorbance of aspirin solution 0.191 Unitless ASPIRIN TABLET CALCULATIONS Part B: Calculations Unrounded Rounded Units 5. Molar concentration of iron salicylate ion in 50 mL volumetric flask (calculated using equation of line) A 4 mol L 6. Molar concentration of iron salicylate ion in 250 mL volumetric flask (parent aspirin stock solution) 6. 4 mol L-1 7. Moles of iron salicylate ion in 250 mL volumetric flask mol (parent aspirin stock solution) 8. Calculated mass of acetylsalicylic acid in the tablet 6. mg 9. Percent error in mass of acetylsalicylic acid in the % tablet
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