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- Which nitrogen atom in the hallucinogenic indole alkaloid N, N-dimethyl-tryptamine is more basic? Explain.TRUE OR FALSE: Reductive amination is a 1-step reaction with a Nu adding to the carbonyl carbon and the intermediate is reduced by NaBH4.When two equivalents of an amine are treated with acetyl chloride, both equivalents of the amine attack the carbonyl group, to give the product shown. 2 O True O False NH₂ CI NH ANH HO + HCI
- Rank the labeled N atoms in the anticancer drug imatinib (trade nameGleevec) in order of increasing basicity. Imatinib, sold as a salt withmethanesulfonic acid (CH3SO3H), is used for the treatment of chronicmyeloid leukemia as well as certain gastrointestinal tumors.the scheme shown consists of key steps in the acidic hydrolysis of an amide. Complete the mechanism by drawing curved arrowsin each stepN-Nitroso amines are stabilized by electron delocalization. Write the two most stable resonance contributors of N-nitrosodimethylamine, (CH3)2NNO.
- What 1° amine and carbonyl compound are needed to prepare each imine?What does the reaction of 4-Chloropentan-2-amine reacted with excess CH3l, Ag2O produce? O Hofmann product only O Zaitsev product only O Both Hofmann and Zaitsev products Equal distributionReductive amination requires a hydrogen on the carbonyl carbon to proceed BECAUSE Reductive amination converts only aldehydes to amines
- (1) Which is the most basic amine and which is a secondary amine? (2) Which can undergo hydrolysis? (3) Which gives a diazonium salt upon reaction with HNO2, HCl at 0oC?Which of the following is the correct order of basicity of amines? A. B > C > AB. A > C > BC. B > A > CD. C > A > BE. A > B > CDraw the product formed when phenylacetic acid (C6H5CH2COOH) istreated with following reagent. With some reagents, no reaction occurs. NH3 , Δ