6) For one mole of Cl2 gas (molar mass 70.91 g/mol, vibrational frequency 560 cm¹, molar entropy 223.1 J mol K-¹) at 298 K and 1 bar, calculate the molecular translational partition function the molecular vibrational partition function (a) (b) qT qv

6) For one mole of Cl2 gas (molar mass 70.91 g/mol, vibrational frequency 560 cm¹, molar entropy 223.1 J mol K-¹) at 298 K and 1 bar, calculate the molecular translational partition function the molecular vibrational partition function (a) (b) qT qv

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter18: More Statistical Thermodynamics

Section: Chapter Questions

Problem 18.4E

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6) For one mole of Cl2 gas (molar mass 70.91 g/mol, vibrational frequency 560 cm¹, molar
entropy 223.1 J mol K-¹) at 298 K and 1 bar, calculate
the molecular translational partition function
the molecular vibrational partition function
the molar internal energy
the rotational partition function
(a)
(b)
(c)
(d)
qT=
qv
Um=
qR

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