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- Calculate the % relative error in solubility by using concentrations instead of activitiesfor Fe(OH)2 in 0.0500 M KNO3 (give the source for thermodynamic solubility).Dibromoethene (DE, p*DE = 22.9 kPa at 358 K) and dibromopropene (DP, p*DP = 17.1 kPa at 358 K) form a nearly ideal solution. If zDE = 0.60, what is (a) ptotal when the system is all liquid, (b) the composition of the vapour when the system is still almost all liquid.The precipitation of Al(OH)3 (Ksp = 1.3 x 10-33) is sometimesused to purify water. (a) Estimate the pH at whichprecipitation of Al(OH)3 will begin if 5.0 lb of Al2(SO4)3is added to 2000 gal of water. (b) Approximately howmany pounds of CaO must be added to the water toachieve this pH?
- The following temperature/composition data were obtained for a mixture of two liquids A and B at 1atm, where x is the mole fraction in the liquid and y the mole fraction in the vapour at equilibrium.T (°C) 110 120 130 140xA 0.73 0.43 0.25 0.10yA 0.96 0.78 0.60 0.36The boiling points are 105°C for A and 150°C for B. What is the composition of the vapour in equilibrium with the liquidof composition (a) xA = 0.35 and (b) xB = 0.25?1. The Ksp of Ca3(PO4)2 is 1.3 × 10−26. Estimate the solubility of this salt in units of g. L−12. If a sample of solid Ca3(PO4)2 is stirred into exactly one litre of a 0.550M solution of Na3PO4, how will the solubility of the salt compare with the answer that you have obtained in question 2.1? Explain you answer in a short sentence.When 2.0 g of aspirin was shaken up in a flask containing two immiscible liquids it was found that the mole fractions in the two liqu ids were 0.11 and 0.18. When a further 1.0 g of aspirin was added, it was found that the mole fraction in the first liquid increased to 0.15. What would you expect the mole fraction in the second liquid to become?
- Derive a general expression that shows pH dependence of the distributioncoefficient defined in (2-20) for a weak acid between a fermentation broth and an organic solvent.Describe the effect, if any the following procedural errors would have on the calculated value of the Ksp. Is the dissolution of Ca(IO3)2 in water endothermic or exothermic? Write an equation for the process, including the heat of reaction.what is the purpose of preparing of a standard sodium hydroxide solution in determination of purity of impure KHP?
- Give techniques on how to produce an ideal precipitate in the analysis of sodium fluoride, NaF with silver nitrate, AgNO3 as precipitant using precipitation gravimetry.A solution is prepared by dissolving 40.00 g of NaCl (f.w. = 58.44 g mol–1), a non-volatile solute, in enough water (m.w. = 18.02 g mol–1) to result in exactly 1 L of solution at 25 °C. Assume the density of the solution is that of pure water (dsolution = 1.000 g mL–1). The ebullioscopic constant (Kb) for water is 0.513 °C m–1. The cryoscopic constant (Kf) for water is 1.86 °C m–1. The vapor pressure of pure water is 0.0313 atm. Find the freezing point of the solution(in C to 2 decimal places)A solution is prepared by dissolving 40.00 g of NaCl (f.w. = 58.44 g mol–1), a non-volatile solute, in enough water (m.w. = 18.02 g mol–1) to result in exactly 1 L of solution at 25 °C. Assume the density of the solution is that of pure water (dsolution = 1.000 g mL–1). The ebullioscopic constant (Kb) for water is 0.513 °C m–1. The cryoscopic constant (Kf) for water is 1.86 °C m–1. The vapor pressure of pure water is 0.0313 atm. Find the vapor pressure of the solution to 3 decimal places in atm.