6. Hydrogen gas is finding more acceptance as an alternative fuel. It is produced along with carbon dioxide by the reaction of carbon monoxide and gaseous water at 915 K. At this temperature, the equilibrium constant (K.) is 1.56. If this reaction is started in a 4.00 L closed system flask with 0.450 mol of CO, 1.25 mol H2O, 1.15 mol CO2, and 3.50 mol H2, calculate the concentrations of all substances in the flask initially and at equilibrium. Put these values in the ICE table below. (Hint: you will need to use the quadratic formula.) CO H20 CO2 H2 (Initial] Change [Equilibrium] a. Write the balanced chemical equation. b. Write the equilibrium expression. c. Calculate the initial concentrations and place these values in the table.

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Chapter12: Chemical Equilibrium
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6. Hydrogen gas is finding more acceptance as an alternative fuel. It is produced along with
carbon dioxide by the reaction of carbon monoxide and gaseous water at 915 K. At this
temperature, the equilibrium constant (K.) is 1.56. If this reaction is started in a 4.00 L closed
system flask with 0.450 mol of CO, 1.25 mol H20, 1.15 mol CO2, and 3.50 mol H2, calculate the
concentrations of all substances in the flask initially and at equilibrium. Put these values in the
ICE table below. (Hint: you will need to use the quadratic formula.)
CO
H20
CO2
H2
(Initial]
Change
(Equilibrium]
a. Write the balanced chemical equation.
b. Write the equilibrium expression.
c. Calculate the initial concentrations and place these values in the table.
d. Calculate the reaction quotient, Q.
e. Express the direction of equilibrium shift as an algebraic expression. Complete the change
row of the table.
f. Substitute the algebraic expressions into the equilibrium expression and solve for the
equilibrium concentrations. Place these values in the table.
g. Check the equilibrium concentrations in the equilibrium expression.
Transcribed Image Text:6. Hydrogen gas is finding more acceptance as an alternative fuel. It is produced along with carbon dioxide by the reaction of carbon monoxide and gaseous water at 915 K. At this temperature, the equilibrium constant (K.) is 1.56. If this reaction is started in a 4.00 L closed system flask with 0.450 mol of CO, 1.25 mol H20, 1.15 mol CO2, and 3.50 mol H2, calculate the concentrations of all substances in the flask initially and at equilibrium. Put these values in the ICE table below. (Hint: you will need to use the quadratic formula.) CO H20 CO2 H2 (Initial] Change (Equilibrium] a. Write the balanced chemical equation. b. Write the equilibrium expression. c. Calculate the initial concentrations and place these values in the table. d. Calculate the reaction quotient, Q. e. Express the direction of equilibrium shift as an algebraic expression. Complete the change row of the table. f. Substitute the algebraic expressions into the equilibrium expression and solve for the equilibrium concentrations. Place these values in the table. g. Check the equilibrium concentrations in the equilibrium expression.
Expert Solution
Step 1

Reaction of Carbon monoxide and gaseous water results in the formation of carbon dioxide and Hydrogen gas.

This Hydrogen gas can be used as an alternative fuel

First we will write balanced reaction and then we will determine equilibrium expression and initial concentrations.

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