6. What is the purpose of adding NaAc to the centrifugate that may contain Cro (procedure 9-12-2)?

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Chapter17: Complexation And Precipitation Reactions And Titrations
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6. What is the purpose of adding NaAc to the centrifugate that may contain Cro
(procedure 9-12-2)?
Transcribed Image Text:6. What is the purpose of adding NaAc to the centrifugate that may contain Cro (procedure 9-12-2)?
9-11 To the centrifugate from procedure 9-9, add dropwise 1M Ba(Ac)2 dropwise, until
precipitation is complete. Centrifuge. Reserve centrifugate for procedure 9-13.
Precipitate may be composed of BaSO4 and BaCrO4.
9-12 Wash precipitate with 10 drops of water and discard washings. Treat precipitate with
9-12-2 Centrifugate may contain CrO. Add 10
2-
4
5 drops of 3M HCI, stir, and centrifuge
9-12-1 Precipitate may be BaSO4. Add 10
drops of 2.5M NaAc. Yellow precipitate
confirms the presence of CrO2-.
drops of 3M HCI. White precipitate
confirms presence of SO
3-
9-13 To 3 drops of centrifugate from procedure 9-11, add 5 drops of AGAC and acidify with
3M HNO3. No precipitation may indicate the presence of CIO3, BO3 NO₂ and NO₂.
Divide centrifugate into four equal portions.
9-13-3
78. Unit 2 Qualitative Chemistry
9-13-1
1st portion
Add 5 drops of
conc. HNO3 and
2 drops of 0.5M
AgNO3 and allow
mixture to stand for
2 min. Centrifuge
and discard any
precipitate formed.
To the centrifugate,
add a few small
crystals of NaNO₂
and stir. Formation
of white precipitate
confirms the
presence of CIO3.
9-13-2
2nd portion
Place the portion in
a casserole. Add 5
drops of conc. H₂SO4
and evaporate
to almost dryness.
Let casserole cool.
Add 10 drops of
methyl alcohol
(CH3OH) and ignite
the whole mixture.
Green bordered
flame confirms the
presence of BO3³.
10%
COMEN
ÓW,noluloz
wolley to
bibligipaiq
entuminos
100X192910
3rd portion
To the centrifugate
in a test tube, add
an equal volume of
urea in HCI solution.
Vigorous evolution of
a gas indicates the
presence of NO₂.
bbA
OH MC 10
no
wo
loz tehly
B0002914
bro
wst 10 200
beroobri
200b Of bbA
hol
JOO***
bno
yol
nf
9-13-4
4th portion
Make two tests for NO3.
a. To 2 drops of
the centrifugate
in a spot plate
depression, add
2 drops of conc.
H₂SO4 and 1 drop of
a-naphthylamine.
Allow it to stand for
3 min. Appearance
of a purple ring
around the drop of
reagent indicates
the presence of
NO3.
ho b. Place a small crystal
of ferrous sulfate
stics in a depression
on armiin of a spot plate.
to pomez Add 2 drops of the
centrifugate and
2 drops of conc.
H₂SO4. Formation of
a brown ring around
the crystal indicates
the presence of
NO₂.
1.
2.
3.
4.
A
Gilre
Holtz
C
Wisn
Zum
Transcribed Image Text:9-11 To the centrifugate from procedure 9-9, add dropwise 1M Ba(Ac)2 dropwise, until precipitation is complete. Centrifuge. Reserve centrifugate for procedure 9-13. Precipitate may be composed of BaSO4 and BaCrO4. 9-12 Wash precipitate with 10 drops of water and discard washings. Treat precipitate with 9-12-2 Centrifugate may contain CrO. Add 10 2- 4 5 drops of 3M HCI, stir, and centrifuge 9-12-1 Precipitate may be BaSO4. Add 10 drops of 2.5M NaAc. Yellow precipitate confirms the presence of CrO2-. drops of 3M HCI. White precipitate confirms presence of SO 3- 9-13 To 3 drops of centrifugate from procedure 9-11, add 5 drops of AGAC and acidify with 3M HNO3. No precipitation may indicate the presence of CIO3, BO3 NO₂ and NO₂. Divide centrifugate into four equal portions. 9-13-3 78. Unit 2 Qualitative Chemistry 9-13-1 1st portion Add 5 drops of conc. HNO3 and 2 drops of 0.5M AgNO3 and allow mixture to stand for 2 min. Centrifuge and discard any precipitate formed. To the centrifugate, add a few small crystals of NaNO₂ and stir. Formation of white precipitate confirms the presence of CIO3. 9-13-2 2nd portion Place the portion in a casserole. Add 5 drops of conc. H₂SO4 and evaporate to almost dryness. Let casserole cool. Add 10 drops of methyl alcohol (CH3OH) and ignite the whole mixture. Green bordered flame confirms the presence of BO3³. 10% COMEN ÓW,noluloz wolley to bibligipaiq entuminos 100X192910 3rd portion To the centrifugate in a test tube, add an equal volume of urea in HCI solution. Vigorous evolution of a gas indicates the presence of NO₂. bbA OH MC 10 no wo loz tehly B0002914 bro wst 10 200 beroobri 200b Of bbA hol JOO*** bno yol nf 9-13-4 4th portion Make two tests for NO3. a. To 2 drops of the centrifugate in a spot plate depression, add 2 drops of conc. H₂SO4 and 1 drop of a-naphthylamine. Allow it to stand for 3 min. Appearance of a purple ring around the drop of reagent indicates the presence of NO3. ho b. Place a small crystal of ferrous sulfate stics in a depression on armiin of a spot plate. to pomez Add 2 drops of the centrifugate and 2 drops of conc. H₂SO4. Formation of a brown ring around the crystal indicates the presence of NO₂. 1. 2. 3. 4. A Gilre Holtz C Wisn Zum
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