7-11. Limestone consists mainly of the mineral calcite, CaCO3. The carbonatecontent of 0.541 3 g of powdered limestone was measured by suspending the powderin water, adding 10.00 mL of 1.396 M HCI, and heating to dissolve the solid and expelCO2:CACO3 (s) +2H* → Ca²* +CO,T +H2OCalcium carbonateFM 100.086The excess acid required 39.96 mL of 0.100 4 M NaOH for complete titration to aphenolphthalein end point. Find the weight percent of calcite in the limestone.

Molarity of NaOH = 0.1004 M Volume of NaOH = 39.96 mL = 0.03996 L ( 1 L = 1000 mL ) Molarity of…

Answered: 7-11. Limestone consists mainly of the…

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter17: Electrochemistry

Section: Chapter Questions

Problem 80AP

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The solubility of borax, which is made up of sodium tetraborate (Na2B4O5(OH)4 8H2O), was analyzed. The dissolution of borax is: Na2B4O5(OH)4 • 8H2O(s) ⇌ 2 Na+(aq) + B4O5(OH)42–(aq) + 8 H2O(l) A 50 mL saturated solution was prepared. After filtration of solution, 5 mL aliquot was transferred to a flask and titrated using 0.432 M HCl. The endpoint was found to be 4.73 mL of the titrant. Tetraborate anion (B4O5(OH)42-) is a weak base which reacts with HCl like the following reaction: B4O5(OH)42–(aq) + 2 H+(aq) + 3 H2O(l) ⇌ 4 H3BO3(aq) What is Ksp expression for the dissolution? What is the tetraborate ions concentration in the filtrate? What is the molar solubility and Ksp of borax if the titration was done at room temperature (298 K)?
The precipitation of Al(OH)3 (Ksp = 1.3 x 10-33) is sometimesused to purify water. (a) Estimate the pH at whichprecipitation of Al(OH)3 will begin if 5.0 lb of Al2(SO4)3is added to 2000 gal of water. (b) Approximately howmany pounds of CaO must be added to the water toachieve this pH?
The hardness of water (hardness count) is usually expressed in parts per million (by mass) of CaCO3. What is the molar concentration of Ca2+ ions in a water sample with a hardness count of 175mg CaCO3il? How many milliliters of concentrated sulfuric acid, 94.0% (w/w), specific gravity of 1.831 are required to prepare 1 liter of a 0.100 M solution? The solubility-product constant for Ce(IO3)3 is 3.2x1010. What is the Ce3+ concentration in a solution prepared by mixing 50.0 ml of 0.0250 M Ce3.. with 50.00 ml of water?
TOPIC: GRAVIMETRY SHOW THE SOLUTION The mercury in a 0.7152-g sample was precipitated with an excess of paraperiodic acid, H5IO6, according to the following reactions:5 Hg+2 + 2 H5IO6 ---> Hg5(IO6)2(s) + 10 H+The precipitate was filtered, washed free of precipitating agent, dried and found to weigh 0.3408-g. Calculate the percentage of Hg2Cl2 in the sample. Molar Masses: Hg5(IO6)2 = 1448.75 Hg2Cl2 = 472.09 Answer: 38.82% Hg2Cl2 An iron ore was analyzed by dissolving a 1.1324-g sample in concentrated HCl. The resulting solution was diluted with water, and the iron (III) was precipitated as the hydrous oxide Fe2O3·xH20 by the addition of NH3. After filtration and washing, the residue was ignited at a high temperature to give 0.5394 g of pure Fe2O3. Calculate (a) % Fe, and (b) % Fe3O4 in the sampleMolar Masses: Fe2O3 = 159.69 Fe = 55.847 Fe3O4 = 231.54 Answer: 33.32% Fe and 46.04% Fe3O4
Potassium acid phthalate, KHC8H4O4 ( MM=204.2 ), reacts with sodium hydroxide on a 1:1 molar basis. A sample of the acid weighing 0.4823 g was titrated with NaOH, requiring 24.35 mL to reach the endpoint. Calculate the molar concentration of the sodium hydroxide solution.
. At 250C, Ksp for AgBr is 5.0 x 10-13. Calculate the solubility of AgBr in g/L at 25 oC (a) in pure water; (b) In the presence of 0.2 mol L−1 NaBr solution
What wt of magnetite should be taken for analysis in order that after converting to a precipitate of Fe2O3.xH2O, the percentage of Fe3O4 in the sample can be found by multiplying the wt in grams of the ignited precipitate (Fe2O3) by 100.
To determine the fluoride content in an aqueous and chloride-containing preparation of ammonium fluoride, the following analysis was performed. 105.2 mg of the preparation was dissolved in 100.0 mL of water. Then a 300 mL 40 mM lead chloride solution was added, whereby all fluoride ions were precipitated out of the solution in the form of the sparingly soluble salt PbClF (s). The precipitate was separated and washed at 15 degrees with a lead fluoride chloride saturated solution and dried at 130 degrees. The precipitate weighed 651.3 mg. a) Calculate the fluoride content (as % by weight F) in the preparation.b) Determine the purity of the ammonium fluoride preparation
Solid aluminum hydroxide (Ksp = 1.3 x 10-33) is added to 3.50 mM Al(NO3)3 solution until there are no solid dissolution. What is the molar solubility of Al(OH)3?
An impure sample of calcium carbonate with a mass of 7.95 g was reacted with 50.00 cm3 of 1.00 mol dm hydrochloric acid (an excess). The resulling solution was transferred to a volumetric flask and titrated with 11.10cm3 of 0.300 mol dm-3 sodium hydroxide solution. Determine the percentage purity by mass of the calcium carbonate sample.CaCO3 + HCl -> CaCl2 + H2O + CO2 HCl + NaOH -> NaCl +H2O a. Determine how many moles of hydrochloric acid were used.b. Determine how many moles of excess HCI was titratedc. Determine how much in moles calcium carbonate present in the sample.d. Calculate the mass of calcium carbonate presente. Determine the percentwge calcium carbonate is in the sample.
As part of a soil analysis on a plot of land, a scientist wants to determine the ammonium content using gravimetric analysis with sodium tetraphenylborate, Na+B(C6H5)4−. Unfortunately, the amount of potassium, which also precipitates with sodium tetraphenylborate, is non‑negligible and must be accounted for in the analysis. Assume that all potassium in the soil is present as K2CO3 and all ammonium is present as NH4Cl. A 5.095 g soil sample was dissolved to give 0.500 L of solution. A 150.0 mL aliquot was acidified and excess sodium tetraphenylborate was added to precipitate both K+ and NH4+ ions completely. B(C6H5)4-+K+⟶KB(C6H5)4(s) B(C6H5)4-+NH4+⟶NH4B(C6H5)4(s) The resulting precipitate amounted to 0.269 g. A new 300.0 mL aliquot of the original solution was made alkaline and heated to remove all of the NH4+ as NH3. The resulting solution was then acidified, and excess sodium tetraphenylborate was added to give 0.129 g of precipitate. Find the mass percentages of NH4Cl and…
Pseudogoutis caused by the formation of calcium diphosphate (Ca2P2O7) crystals in tendons, cartilage and ligaments, usually occurring if diphosphate levels in blood plasma 7 become very If the [Ca2+] in blood plasma is 9.2 mg/dL and Ksp for Ca2P2O7 is 8.64 x 10-13, what is the minimum concentration of diphosphate P2O 4- necessary for precipitation?

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