7.) Electrochemical cell potentials can be used to determine equilibrium constants that would be otherwise difficult to determine because concentrations are small. Calculate the value of Ksp for CdS from the following data. Assume T = 298 K. CaS (s) + 2e- < -D> Cd(s) + S?(аq) Е 3 -1.21 V Cd2*(aq) + 2e- <==> Cd(s) E° = -0.40 V а. 3 x 10° b. 4 x 10-28 с. 2 х 10-14 d. 3 x 10+27 е. 1 х 10:36

Fundamentals Of Analytical Chemistry
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Chapter22: Bulk Electrolysis: Electrogravimetry And Coulometry
Section: Chapter Questions
Problem 22.28QAP
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7.) Electrochemical cell potentials can be used to determine equilibrium constants that
would be otherwise difficult to determine because concentrations are small. Calculate the
value of Ksp for CdS from the following data. Assume T = 298 K.
CdS(s) + 2e- <= => Cd(s) + S²(aq) E°=-1.21 V
Cd2*(aq) + 2e-<==> Cd(s)
E° = -0.40 V
а. 3 x 10:55
b. 4 x 10-28
с. 2х 10-14
d. 3 x 10+27
е. 1 х 10-36
Transcribed Image Text:7.) Electrochemical cell potentials can be used to determine equilibrium constants that would be otherwise difficult to determine because concentrations are small. Calculate the value of Ksp for CdS from the following data. Assume T = 298 K. CdS(s) + 2e- <= => Cd(s) + S²(aq) E°=-1.21 V Cd2*(aq) + 2e-<==> Cd(s) E° = -0.40 V а. 3 x 10:55 b. 4 x 10-28 с. 2х 10-14 d. 3 x 10+27 е. 1 х 10-36
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