7. The rate constant for the hydrolysis of a m-chloro substituted and p-methoxy substituted organic substance are 0.50 and 0.015 at 25 °C, respectively. The o values of m-Cl and p-OMe are +0.37 and -0.27, respectively. Calculate the reaction constantp and rate constant for hydrolysis of unsubsituted substance and p-nitro (o = + 0.75) substituted substance. %3D

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter9: Nucleophilic Substitution And Β-elimination
Section: Chapter Questions
Problem 9.36P
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7. The rate constant for the hydrolysis of a m-chloro substituted and p-methoxy
substituted organic substance are 0.50 and 0.015 at 25 °C, respectively. The o
values of m-Cl and p-OMe are +0.37 and -0.27, respectively. Calculate the
reaction constantp and rate constant for hydrolysis of unsubsituted substance
and p-nitro (6 = + 0.75) substituted substance.
Transcribed Image Text:7. The rate constant for the hydrolysis of a m-chloro substituted and p-methoxy substituted organic substance are 0.50 and 0.015 at 25 °C, respectively. The o values of m-Cl and p-OMe are +0.37 and -0.27, respectively. Calculate the reaction constantp and rate constant for hydrolysis of unsubsituted substance and p-nitro (6 = + 0.75) substituted substance.
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