7:38 Question 35 of 36 LTE 76 Submit A 'H NMR spectrum is shown for a molecule with the molecular formula of C9H10O2. Draw the structure that best fits this data.
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- Provide the structure or SMILES of the compound with molecular formula C8H8O and correlates with the NMR shown in the imageCompound P has molecular formula C5H9ClO2. Deduce the structure of Pfrom its 1H and 13C NMR spectra.Propose a structure for D (molecular formula C9H9ClO2) consistent withthe given spectroscopic data. 13C NMR signals at 30, 36, 128, 130, 133,139, and 179 ppm
- Propose a structure for D (molecular formula C9H9ClO2) consistent with the given spectroscopic data. 13C NMR signals at 30, 36, 128, 130, 133, 139, and 179 ppmA compound reacts with methylmagnesium bromide followed by acidification to form the product with the following 1H NMR spectrum. Identify thecompound.Identify the structures of D and E, isomers of molecular formulaC6H12O2, from their IR and 1H NMR data. Signals at 1.35 and 1.60 ppm inthe 1H NMR spectrum of D and 1.90 ppm in the 1H NMR spectrum of Eare multiplets.
- Treatment of butan-2-one (CH3COCH2CH3) with strong base followed byCH3I forms a compound Q, which gives a molecular ion in its massspectrum at 86. The IR (> 1500 cm−1 only) and 1H NMR spectra of Q aregiven below. What is the structure of Q?You have a sample of a compound of molecular formula C11H15NO2, which has a benzene ring substituted by two groups, (CH3)2N− and −CO2CH2CH3, and exhibits the given 13C NMR. What disubstituted benzene isomer corresponds to these 13C data?You have a sample of a compound of molecular formula C11H15NO2, which has a benzene ring substituted by two groups, (CH3)2N – and – CO2CH2CH3, and exhibits the given 13C NMR. What disubstituted benzene isomer corresponds to these 13C data?
- A compound with molecular formula C5H10Br2 displays the following 13C NMR along with the DEPT-90 and DEPT-135 13CNMR spectra. What is the structure for this compound?what is is the structure of a compound of molecular formula c 10 h 14 o 2 that shows a strong ir absorption at 3150-2850 cm − 1 and give the following 1 h nmr absorptions: 1.4 (triplet, 6 h), 4.0 (quarter, 4h), and 6.8 (singlet, 4h) ppm?When 2-bromo-3,3-dimethylbutane is treated with K+ −OC(CH3)3, a singleproduct T having molecular formula C6H12 is formed. When 3,3-dimethylbutan-2-ol is treated with H2SO4, the major product U has thesame molecular formula. Given the following 1H NMR data, what are thestructures of T and U? Explain in detail the splitting patterns observedfor the three split signals in T.1H NMR of T: 1.01 (singlet, 9 H), 4.82 (doublet of doublets, 1 H, J = 10, 1.7 Hz), 4.93 (doublet of doublets, 1 H, J = 18, 1.7 Hz), and 5.83 (doublet ofdoublets, 1 H, J = 18, 10 Hz) ppm1H NMR of U: 1.60 (singlet) ppm Additional problems on the spectroscopy of alkenes are given in Chapters A–C:Mass spectrometry: A.16b, A.20, A.23Infrared spectroscopy: B.5, B.7(A), B.12c, B17a, B.18cNuclear magnetic resonance spectroscopy: C.12a; C.15d, e; C.29d; C.32d;C.37; C.38d, f; C.43i, j; C.44; C.45; C.49d, f; C.50b; C.51c; C.55