8. In each of the following pairs, circle the quantity that is greater; if the two items are the same, circle SAME. a. electronegativity of chlorine electronegativity of arsenic # of unpaired electrons in Mn²+ # of unpaired electrons in As # of orbitals in 5p subshell # of 4p electrons in Se²- # of nonbonding domains on the central atom in T-shaped molecular geometry b. c. d. # of orbitals in 3p subshell # of 4p electrons in Rb+ or or or or e. # of nonbonding domains on the central atom in square pyramidal molecular geometry or or or or or or SAME SAME SAME SAME SAME NG & OL up

Organic Chemistry: A Guided Inquiry
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ISBN:9780618974122
Author:Andrei Straumanis
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Chapter17: Conjugation And Molecular Orbital (mo) Theory
Section: Chapter Questions
Problem 10E
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Answer the following questions
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8.
10.
In each of the following pairs, circle the quantity that is greater; if the two items are the same, circle SAME.
electronegativity of chlorine
electronegativity of arsenic
# of unpaired electrons in Mn²+
# of unpaired electrons in As
# of orbitals in 5p subshell
# of 4p electrons in Se²-
# of nonbonding domains on the central
atom in T-shaped molecular geometry
a.
b.
c.
d.
a.
b.
C.
d.
e.
e. # of nonbonding domains on the central
atom in square pyramidal molecular geometry
# of orbitals in 3p subshell
# of 4p electrons in Rb+
sp²
lyi
sp³d²
bond 1
hybridization
of central atom
or
9. The structure of lidocaine (C14H22N₂O), a common local anesthetic, is shown below. Answer the following questions
about this structure. Lone pairs of electrons have been omitted for clarity; all atoms (except H) obey the octet rule; bond
angles may not be as they appear.
CH₂
Determine the number of sp² hybridized atoms.
Determine the number of pi (7) bonds.
Consider the N-C-C bond angles labeled a and b. Which of these is the
larger angle? Circle the one best answer.
angle a
angle b
bond 4
or
or
electron domain
geometry
octahedral
or
trigonal planar
or
Now consider the C- O bond labelled 3.
What orbitals overlap to form the C- O sigma bond?
What orbitals overlap to form the C- O pi bond?
they are the same
they are the same length
Fill in the blanks to complete the following table for substances with the chemical formula AX,.
clinc
#bonding
domains.
Consider the C-C bonds labelled 1 and 4. Which of these bonds should be shorter? Circle the one best answer
below.
# nonbonding
domains
0
HC
1
HC
orbital on C with
orbital on C with
or
molecular geometry
or
see-saw
or
or
or
SAME
val
SAME
SAME
SAME
SAME
H₂C2
orbital on O
orbital on O
polar or nonpolar?
polar
CH₂
41
VORMI
CH₂
NG & OL
up
*
9
up
Z
dn
el
Transcribed Image Text:% 8. 10. In each of the following pairs, circle the quantity that is greater; if the two items are the same, circle SAME. electronegativity of chlorine electronegativity of arsenic # of unpaired electrons in Mn²+ # of unpaired electrons in As # of orbitals in 5p subshell # of 4p electrons in Se²- # of nonbonding domains on the central atom in T-shaped molecular geometry a. b. c. d. a. b. C. d. e. e. # of nonbonding domains on the central atom in square pyramidal molecular geometry # of orbitals in 3p subshell # of 4p electrons in Rb+ sp² lyi sp³d² bond 1 hybridization of central atom or 9. The structure of lidocaine (C14H22N₂O), a common local anesthetic, is shown below. Answer the following questions about this structure. Lone pairs of electrons have been omitted for clarity; all atoms (except H) obey the octet rule; bond angles may not be as they appear. CH₂ Determine the number of sp² hybridized atoms. Determine the number of pi (7) bonds. Consider the N-C-C bond angles labeled a and b. Which of these is the larger angle? Circle the one best answer. angle a angle b bond 4 or or electron domain geometry octahedral or trigonal planar or Now consider the C- O bond labelled 3. What orbitals overlap to form the C- O sigma bond? What orbitals overlap to form the C- O pi bond? they are the same they are the same length Fill in the blanks to complete the following table for substances with the chemical formula AX,. clinc #bonding domains. Consider the C-C bonds labelled 1 and 4. Which of these bonds should be shorter? Circle the one best answer below. # nonbonding domains 0 HC 1 HC orbital on C with orbital on C with or molecular geometry or see-saw or or or SAME val SAME SAME SAME SAME H₂C2 orbital on O orbital on O polar or nonpolar? polar CH₂ 41 VORMI CH₂ NG & OL up * 9 up Z dn el
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