9. Calculate the standard electrode potential for the aqueous couple [Fe(ox):]*(aq)/[Fe(ox):]+(aq) from the following data (298 K), where ox?- refers to the oxalate anion, C204?-: Fe*(aq) + e = Fe2*(aq) E° = +0.770 V Fe2* (aq) + 3 ох?- [Fe(ox);] (aq) K = 1.7 x 105 Fe3+ (aq) + 3 ox² = [Fe(ox)3]³ (aq) K= 2.0 x 1020

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter22: An Introduction To Electroanalytical Chemistry
Section: Chapter Questions
Problem 22.1QAP: Calculate the electrode potentials of the following half-cells. (a) Ag+(0.0436 M)|Ag (b) Fe3+ (5.34 ...
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9. Calculate the standard electrode potential for the aqueous couple
[Fe(ox):]*(aq)/[Fe(ox):]+(aq)
from the following data (298 K), where ox?- refers to the oxalate anion, C204-:
Fe*(aq) + e = Fe2"(aq)
E° = +0.770 V
Fe2+ (aq) + 3 ox² = [Fe(ox)3]+(aq)
K = 1.7 x 105
Fe3+ (aq) + 3 ox?= [Fe(ox)3]³-(aq)
K= 2.0 x 102º
Transcribed Image Text:9. Calculate the standard electrode potential for the aqueous couple [Fe(ox):]*(aq)/[Fe(ox):]+(aq) from the following data (298 K), where ox?- refers to the oxalate anion, C204-: Fe*(aq) + e = Fe2"(aq) E° = +0.770 V Fe2+ (aq) + 3 ox² = [Fe(ox)3]+(aq) K = 1.7 x 105 Fe3+ (aq) + 3 ox?= [Fe(ox)3]³-(aq) K= 2.0 x 102º
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