9. R. Aveyard & co-workers (J. Chem. Soc., Farad Trans., 86, 211 ( 1990 ) have measured the surface tension ( ) of the cationic surfactant, dodecyltrimethylammonium bromide (D0TAB) at various concentrations at 298K. DOTAB [mol.dm-3] .0025 .0032 .0041 .0052 .0067 .0086 .0111 o [ mN.m-1 ] 59.3 56.8 54.3 50.0 47.3 44.6 41.2 Given that both the cation and anion of DOTAB are adsorbed at the surface (absence of inert electrolyte), calculate the surface excess, D, in molecules / m2. Slrete whi ult fror f DoT AD 9utlining

Principles of Instrumental Analysis
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Chapter29: Supercritical Fluid Chromatography And Extraction
Section: Chapter Questions
Problem 29.11QAP
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9.
R. Aveyard & co-workers (J. Chem. Soc., Farad Trans., 86, 211 ( 1990 ) have
measured the surface tension ( ) of the cationic surfactant, dodecyltrimethylammonium
bromide (D0TAB) at various concentrations at 298K.
DOTAB [mol.dm-3]
.0025
.0032
.0041
.0052
.0067 .0086
.0111
o [ mN.m-1 ]
59.3
56.8
54.3
50.0
47.3
44.6
41.2
Given that both the cation and anion of D0TAB are adsorbed at the surface
(absence of inert electrolyte), calculate the surface excess, D, in
molecules / m2.
Sketch the -A curve which might result from the adsorption of D0TAB outlining the
reason for your proposed choice.
Transcribed Image Text:9. R. Aveyard & co-workers (J. Chem. Soc., Farad Trans., 86, 211 ( 1990 ) have measured the surface tension ( ) of the cationic surfactant, dodecyltrimethylammonium bromide (D0TAB) at various concentrations at 298K. DOTAB [mol.dm-3] .0025 .0032 .0041 .0052 .0067 .0086 .0111 o [ mN.m-1 ] 59.3 56.8 54.3 50.0 47.3 44.6 41.2 Given that both the cation and anion of D0TAB are adsorbed at the surface (absence of inert electrolyte), calculate the surface excess, D, in molecules / m2. Sketch the -A curve which might result from the adsorption of D0TAB outlining the reason for your proposed choice.
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