914. Normal heptane is dehydrocyclicized to toluene and hydrogen in a continuous vapor-phase reaction: 2 >C7H16 → C6H5CH3 + 4 H₂ Tom D Pure heptane at 400°C is fed to the reactor. The reactor operates isothermally at 400°C and the reaction goes to completion. Data: The average heat capacity of n-heptane beween 25°C and 400°C is 0.2427 kJ/(mol. °C). (a) Taking a basis of 1 mol of heptane fed, draw and label a flowchart. (b) Taking elemental species [C(s), H₂(g)] at 25°C as references, prepare and fill in an inlet-outlet enthalpy table. (See Example 9.5-2.) (c) Calculate the required heat transfer to or from the reactor (state which it is) in kJ. (d) What is the heat of the heptane dehydrocyclization reaction (AĤ,) at 400°C and 1 atm?

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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914. Normal heptane is dehydrocyclicized to toluene and hydrogen in a continuous vapor-phase reaction:
C7H16 CH3CH3 + 4H₂
Pure heptane at 400°C is fed to the reactor. The reactor operates isothermally at 400°C and the
reaction goes to completion. Data: The average heat capacity of n-heptane beween 25°C and 400°C
is 0.2427 kJ/(mol. °C).
(a) Taking a basis of 1 mol of heptane fed, draw and label a flowchart.
(b) Taking elemental species [C(s), H₂(g)] at 25°C as references, prepare and fill in an inlet-outlet
enthalpy table. (See Example 9.5-2.)
Calculate the required heat transfer to or from the reactor (state which it is) in kJ.
(d) What is the heat of the heptane dehydrocyclization reaction (AĤ,) at 400°C and 1 atm?
1°
Transcribed Image Text:914. Normal heptane is dehydrocyclicized to toluene and hydrogen in a continuous vapor-phase reaction: C7H16 CH3CH3 + 4H₂ Pure heptane at 400°C is fed to the reactor. The reactor operates isothermally at 400°C and the reaction goes to completion. Data: The average heat capacity of n-heptane beween 25°C and 400°C is 0.2427 kJ/(mol. °C). (a) Taking a basis of 1 mol of heptane fed, draw and label a flowchart. (b) Taking elemental species [C(s), H₂(g)] at 25°C as references, prepare and fill in an inlet-outlet enthalpy table. (See Example 9.5-2.) Calculate the required heat transfer to or from the reactor (state which it is) in kJ. (d) What is the heat of the heptane dehydrocyclization reaction (AĤ,) at 400°C and 1 atm? 1°
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