9a. Give a complete reaction scheme for the polymerization of styrene with tert-butylhydroperoxide as an initiator and termination by disproportionate. The structures of some important polyamides used in various industriesand their melting temperature, Tm are shown in Table 1.Table 1N-(CH2)6-N-C-{CH2)4-264 °CNylon 66to(CH2)e-N-(CH2la-215 °CNylon 610-N-(CH2ls-C.223 °CNylon 6>300 °CNomex>300 °CKevlar

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Answered: 9a. Give a complete reaction scheme for…

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter24: Amines And Heterocycles

Section24.SE: Something Extra

Problem 40MP

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9a. Give a complete reaction scheme for the polymerization of styrene with tert-butylhydroperoxide as an initiator and termination by disproportionate.

The structures of some important polyamides used in various industries
and their melting temperature, Tm are shown in Table 1.
Table 1
N-(CH2)6-N-C-{CH2)4-
264 °C
Nylon 66
to
(CH2)e-N-
(CH2la-
215 °C
Nylon 610
-N-(CH2ls-C.
223 °C
Nylon 6
>300 °C
Nomex
>300 °C
Kevlar

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

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