A 0.15 M aqueous solution of the chloride salt of the complex ion Pt(NH3 )42+ is found to be weakly acidic with a pH of 4.92. This is initially puzzling because the Cl2 ion in water is not acidic and NH3 in water is basic, not acidic.Finally, it is suggested that the Pt(NH3 )42+ ion as a group donates hydrogen ions. Compute the Ka of this acid, assuming that just one hydrogen ion is donated.

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
Section20.6: Coordinate Covalent Bonds: Complex Ions And Coordination Compounds
Problem 20.8CE
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A 0.15 M aqueous solution of the chloride salt of the complex ion Pt(NH3 )42+ is found to be weakly acidic with a pH of 4.92. This is initially puzzling because the Cl2 ion in water is not acidic and NH3 in water is basic, not acidic.
Finally, it is suggested that the Pt(NH3 )42+ ion as a group donates hydrogen ions. Compute the Ka of this acid, assuming that just one hydrogen ion is donated.

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