A 20.00 mL aliquot of sorbic acid solution (HC6H7O2) was titrated with 0.0985 M NaOH * (aq) using both an indicator and a pH meter. Ka (HC6H7O2) , is 1.7*10^ -5 . A total of 25.34 mL of 0.0985 M NaOH * (aq) was required to reach the equivalence point a) Calculate the molarity of the sorbic acid solution. b) Calculate the pH of the sorbic acid solution (use the RICE table) . c) .Calculate the pH and [C6H 7 O 2-] at the half-equivalence point .
A 20.00 mL aliquot of sorbic acid solution (HC6H7O2) was titrated with 0.0985 M NaOH * (aq) using both an indicator and a pH meter. Ka (HC6H7O2) , is 1.7*10^ -5 . A total of 25.34 mL of 0.0985 M NaOH * (aq) was required to reach the equivalence point a) Calculate the molarity of the sorbic acid solution. b) Calculate the pH of the sorbic acid solution (use the RICE table) . c) .Calculate the pH and [C6H 7 O 2-] at the half-equivalence point .
Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter18: Electrochemistry
Section: Chapter Questions
Problem 18.103QE
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A 20.00 mL aliquot of sorbic acid solution (HC6H7O2) was titrated with 0.0985 M NaOH * (aq) using both an indicator and a pH meter. Ka (HC6H7O2) , is 1.7*10^ -5 . A total of 25.34 mL of 0.0985 M NaOH * (aq) was required to reach the equivalence point
a) Calculate the molarity of the sorbic acid solution.
b) Calculate the pH of the sorbic acid solution (use the RICE table) .
c) .Calculate the pH and [C6H 7 O 2-] at the half-equivalence point .
d) Calculate the pH at the equivalence point of the titration . (use Kb for hydrolysis of sorbate anion and RICE table ).
e)Suggest an appropriate indicator for titration . Explain your choice .
f) Calculate the pH of the solution after 10.00 mL of 0.0985 M NaOH * (aq) was added . (find moles of sorbic acid and sorbate and use Henderson Haselbalch equation )
Indicator pKa
Phenolphthalein 9.3
Bromothymol blue 7.0
Methyl red. 5.0
Thymol blue. 2.0
Methyl violet 0.80
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