A 20.00 mL solution of 0.1200 M TI³+ is titrated with 0.2000 M Fe²+. TI³+ + 2e- TI* Eº = +1.280 V Fe³+ + e- Fe²+ Eº = +0.771 V

Fundamentals Of Analytical Chemistry
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Chapter19: Applications Of Standard Electrode Potentials
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3. A 20.00 mL solution of 0.1200 M TI³+ is titrated with 0.2000 M Fe²+.
TI³+ + 2e- TI*
Eº = +1.280 V
Fe³+ + e-
Fe²+
Eº = +0.771 V
a) Write the balanced equation for the titration reaction of T1³+ with Fe²+.
b) Calculate the electrode potential after addition of 10.00 mL of titrant.
c) Calculate the electrode potential after addition of 30.00 mL of titrant.
Transcribed Image Text:3. A 20.00 mL solution of 0.1200 M TI³+ is titrated with 0.2000 M Fe²+. TI³+ + 2e- TI* Eº = +1.280 V Fe³+ + e- Fe²+ Eº = +0.771 V a) Write the balanced equation for the titration reaction of T1³+ with Fe²+. b) Calculate the electrode potential after addition of 10.00 mL of titrant. c) Calculate the electrode potential after addition of 30.00 mL of titrant.
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