(a) (b) (c) d[B] dt State the differential equation for given by mass action kinetics. Use the Principle of Superposition to find the general solution of the ODE for What values of the arbitrary constant C in your solution from (b) give physically realistic solutions? (d) Given that the reaction vessel initially contains no A or B, find expressions for [A](t) and [B](t) in terms of t, k and r.

Chemistry: An Atoms First Approach
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Author:Steven S. Zumdahl, Susan A. Zumdahl
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Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 5ALQ: Consider the following statements: In general, the rate of a chemical reaction increases a bit at...
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1.
A substance A is added at a constant rate r M s-¹ to a reaction vessel, in which it decays by mass
action kinetics according to the reaction
A2B.
Let t be the time in seconds since the start of the reaction, and let [A] and [B] be measured in M.
The concentration [A] is described by the ODE
(a)
(b)
(c)
d[A]
dt
= r - k[A].
State the differential equation for [B] given by mass action kinetics.
dt
d[A]
Use the Principle of Superposition to find the general solution of the ODE for A
What values of the arbitrary constant C in your solution from (b) give physically realistic
solutions?
(d)
Given that the reaction vessel initially contains no A or B, find expressions for [A](t) and [B](t)
in terms of t, k and r.
Transcribed Image Text:1. A substance A is added at a constant rate r M s-¹ to a reaction vessel, in which it decays by mass action kinetics according to the reaction A2B. Let t be the time in seconds since the start of the reaction, and let [A] and [B] be measured in M. The concentration [A] is described by the ODE (a) (b) (c) d[A] dt = r - k[A]. State the differential equation for [B] given by mass action kinetics. dt d[A] Use the Principle of Superposition to find the general solution of the ODE for A What values of the arbitrary constant C in your solution from (b) give physically realistic solutions? (d) Given that the reaction vessel initially contains no A or B, find expressions for [A](t) and [B](t) in terms of t, k and r.
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