A buffer solution is formed by adding 0.200 moles of solid potassium nitrite, KNO₂, to 500.0 ml of 0.500 M Nitrous acid, HNO₂ solution. You may assume that the change in volume is negligible upon addition of the solid. pKa of HNO2 is 3.40 Ka of HNO2 is 4.0E-4 m.w. of HNO2 is 47.01 g/mol pH of the buffer solution is 3.30, so now Calculate the pH of the buffer solution after the addition of 5.00 ml of 2.50 M Ba(OH)₂.

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter15: Complex Ion And Precipitation Equilibria
Section: Chapter Questions
Problem 14QAP: A buffer solution is prepared by adding 5.50 g of ammonium chloride and 0.0188 mol of ammonia to...
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A buffer solution is formed by adding 0.200 moles of solid potassium nitrite, KNO₂, to 500.0 ml of 0.500 M Nitrous acid, HNO₂ solution. You may assume that the change in volume is negligible upon addition of the solid.

pKa of HNO2 is 3.40

Ka of HNO2 is 4.0E-4

m.w. of HNO2 is 47.01 g/mol

pH of the buffer solution is 3.30, so now

Calculate the pH of the buffer solution after the addition of 5.00 ml of 2.50 M Ba(OH)₂.

 

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