A chemical engineer is studying the following reaction: HCH,CO,(aq)+CH;NH,(aq) → CH;CO,(aq)+CH;NH,(aq) At the temperature the engineer picks, the equilibrium constant K for this reaction is 1.1. The engineer charges ("fills") four reaction vessels with acetic acid and methylamine, and lets the reaction begin. She then measures the composition of the mixture inside each vessel from time to time. Her first set of measurements are shown inn the table below. Predict the changes in the compositions the engineer should expect next time she measures the compositions. Ar reaction compound concentration expected change in concentration vessel HCH,CO, 0.35 M O f increase O I decrease O (no change) CH,NH, 0.21 M f increase I decrease (no change) A CH,Co, O (no change) 1.05 M ↑ increase O I decrease CH,NH, 1.00 M O f increase O I decrease O (no change) HCH,CO, 0.71 M f increase OI decrease (no change) CH,NH, 0.57 M O f increase OI decrease O (no change) В CH,CO, 0.69 M O t increase O I decrease O (no change)

Chemistry for Engineering Students
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Chapter12: Chemical Equilibrium
Section: Chapter Questions
Problem 12.40PAE: Because carbonic acid undergoes a second ionization, the student in Exercise 12.39 is concerned that...
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HCH,CO,
0.71 M
f increase
I decrease
(no change)
CH,NH,
0.57 M
f increase
I decrease
(no change)
CH,CO,
0.69 M
f increase
I decrease
(no change)
CH,NH,
0.64 M
I decrease
(no change)
increase
HCH,CO,
1.07 M
f increase
I decrease
(no change)
CH,NH,
0.93 M
↑ increase
I decrease
(no change)
CH,CO,
0.33 M
f increase
I decrease
(no change)
CH,NH,
0.28 M
↑ increase
I decrease
(no change)
?
Transcribed Image Text:HCH,CO, 0.71 M f increase I decrease (no change) CH,NH, 0.57 M f increase I decrease (no change) CH,CO, 0.69 M f increase I decrease (no change) CH,NH, 0.64 M I decrease (no change) increase HCH,CO, 1.07 M f increase I decrease (no change) CH,NH, 0.93 M ↑ increase I decrease (no change) CH,CO, 0.33 M f increase I decrease (no change) CH,NH, 0.28 M ↑ increase I decrease (no change) ?
A chemical engineer is studying the following reaction:
HCH;CO,(aq)+CH,NH,(aq) → CH;CO,(aq)+CH,NH,(aq)
At the temperature the engineer picks, the equilibrium constant K, for this reaction is 1.1.
The engineer charges ("fills") four reaction vessels with acetic acid and methylamine, and lets the reaction begin. She then
measures the composition of the mixture inside each vessel from time to time. Her first set of measurements are shown no
the table below.
Predict the changes in the compositions the engineer should expect next time she measures the compositions.
Ar
reaction
compound
concentration
expected change in concentration
vessel
HCH,CO,
0.35 M
f increase
I decrease
(no change)
CH,NH,
0.21 M
f increase
I decrease
(no change)
A
CH,CO,
1.05 M
f increase
I decrease
(no change)
+
CH,NH,
1.00 M
f increase
I decrease
(no change)
HCH;CO,
0.71 M
f increase
I decrease
(no change)
CH,NH,
0.57 M
f increase
I decrease
(no change)
В
CH,CO,
0.69 M
f increase
O I decrease
(no change)
Transcribed Image Text:A chemical engineer is studying the following reaction: HCH;CO,(aq)+CH,NH,(aq) → CH;CO,(aq)+CH,NH,(aq) At the temperature the engineer picks, the equilibrium constant K, for this reaction is 1.1. The engineer charges ("fills") four reaction vessels with acetic acid and methylamine, and lets the reaction begin. She then measures the composition of the mixture inside each vessel from time to time. Her first set of measurements are shown no the table below. Predict the changes in the compositions the engineer should expect next time she measures the compositions. Ar reaction compound concentration expected change in concentration vessel HCH,CO, 0.35 M f increase I decrease (no change) CH,NH, 0.21 M f increase I decrease (no change) A CH,CO, 1.05 M f increase I decrease (no change) + CH,NH, 1.00 M f increase I decrease (no change) HCH;CO, 0.71 M f increase I decrease (no change) CH,NH, 0.57 M f increase I decrease (no change) В CH,CO, 0.69 M f increase O I decrease (no change)
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