A chemical reaction proceeds with a decrease in both enthalpy and entropy. This reaction will be spontaneous when ∆H=T∆S Answer ii) Spontaneous change is accompanied by an increase in internal energy or enthalpy. Answer iii) The entropy of a system and its surroundings always increases for a spontaneous change. Answer

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter13: Spontaneous Processes And Thermodynamic Equilibrium
Section: Chapter Questions
Problem 20P
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her the following statements are TRUE or FALSE

i) A chemical reaction proceeds with a decrease in both enthalpy and entropy. This reaction will be spontaneous when ∆H=T∆S Answer

ii) Spontaneous change is accompanied by an increase in internal energy or enthalpy. Answer

iii) The entropy of a system and its surroundings always increases for a spontaneous change. Answer

iv) The efficiency of a heat engine is maximum when the temperature of the source is minimum and that of the sink is maximum. Answer

v) The efficiency of a heat engine operating between 1000 K and 200 K is greater than the engine operating between 1000 K and 500 K. Answer

 

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