a) Chlorine is disproportionate in basic medium. And in an acid medium? Write both reactions and calculate the final potential, indicating if they are thermodynamically favorable (See Frost diagram) ClO- /Cl2 = 0.42 V HClO /Cl2 = 1.63 V Cl2 /Cl- = 1.36 V b) Use the Latimer diagram of chlorine in acid medium to determine the potential corresponding to the reduction of ClO4 - to Cl2. Write the fitted equation of this reaction.
a) Chlorine is disproportionate in basic medium. And in an acid medium? Write both reactions and calculate the final potential, indicating if they are thermodynamically favorable (See Frost diagram) ClO- /Cl2 = 0.42 V HClO /Cl2 = 1.63 V Cl2 /Cl- = 1.36 V b) Use the Latimer diagram of chlorine in acid medium to determine the potential corresponding to the reduction of ClO4 - to Cl2. Write the fitted equation of this reaction.
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter4: Energy And Chemical Reactions
Section: Chapter Questions
Problem 4.ECP
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a) Chlorine is disproportionate in basic medium. And in an acid medium? Write both reactions and calculate the final potential, indicating if they are
ClO- /Cl2 = 0.42 V HClO /Cl2 = 1.63 V Cl2 /Cl- = 1.36 V
b) Use the Latimer diagram of chlorine in acid medium to determine the potential corresponding to the reduction of ClO4 - to Cl2. Write the fitted equation of this reaction.
Transcribed Image Text:+7
+5
+4
+1
+1.175
+1.188
+1.659
+1.201
+1.181
+1.674
+1.630
+1.358
Cio,-
→Clo,
→ HČIÓ,-
HCIO
+1.468
12
10
CIO
8
co;
HCIO20
HCIO
2
Cio, cio,
OCIO
Ocr
-1 0
1 2 3 4 5
6 7
4,
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