(a) Construct an MO diagram for the formation of O2; use only the valence orbitals of the oxygen atoms. (b) Use the diagram to rationalize the following trend in 0–0 bond distances: O2, 121 pm; [O,]*, 112 pm; [O]¯, 134 pm; [O,]°¯, 149 pm. (c) Which of these species are paramagnetic?

(a) Construct an MO diagram for the formation of O2; use only the valence orbitals of the oxygen atoms. (b) Use the diagram to rationalize the following trend in 0–0 bond distances: O2, 121 pm; [O,]*, 112 pm; [O]¯, 134 pm; [O,]°¯, 149 pm. (c) Which of these species are paramagnetic?

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Related questions

Q: 3.- Draw the structure of S203 ion, and indicate the hybridization

A: Central sulfur is sp3 hybridized and terminal sulfur is sp2 hybridized.

Q: The sulfate ion can be represented with four S-O bonds or with two S-O and two So=O bonds.(a) Which…

A: Since you have posted multiple sub-parts, the answer for first three sub-parts are given below.…

Q: Explain in detail why a catalyst is used to produce SO3.

A: Solution- SO3 is produced by the oxidation of SO2 .This was done during contact process.H usually a…

Q: How many of carbons 2p orbitals are left unhybridized in CO2? 2.

A: To determine the number of unhybridized 2p orbitals of C in CO2

Q: Based on its molecular orbital diagram, is peroxide ion O22- paramagnetic or diamagnetic?

A: Given, Based on its molecular orbital diagram, is peroxide ion O22- paramagnetic or diamagnetic ?

Q: How does 14Si have the same valence of 126C ?

A: A group in a periodic table is the vertical column of elements having the same chemical properties…

Q: Thallium forms the compound TlI₃. What is the apparentoxidation state of Tl in this compound? Given…

Q: Why do stable xenon flourides have an even number of F atoms?

A: The term electronic configuration can be defined as the distribution of electrons of a given atom or…

Q: draw the structure of of Fe2(SO4)3.

Q: How do the acidities of aqueous solutions of Tl₂O and Tl₂O₃ compare with each other? Explain.

A: Concept introduction: Acidic substance are those substance which has pH is lower than 7. Basic…

Q: 4. Give two aspects that need to be fulfilled when you look at the structure of a dye made by diazo…

A: The use of diazo compounds as dye pigment are known since several decades.The structural aspects of…

Q: hich of the following statements is false regarding hydrogen peroxide? Reaction of H2O2 with Fe2+…

A: Reaction of H2O2 with Fe2+ ions will generate OH radicals. See the written solution

Q: In the methoxide anion (CH3O-), is it possible for a double bond to exist between C and O, given…

Q: Provide two aspects that need to be fulfilled when you look at the structure of a dye made by diazo…

Q: likely to be silicon doped with Antimony Sb?

Q: What atomic or hybrid orbitals make up the bond between C and O in carbon dioxide, CO2 ?

A: Chemical Bond: It is place where the electron density is high. Bonding can take place by sharing or…

Q: What methods could be used to determine the structure of polyiodides? Discuss how could they…

A: Answer - polyiodides - The polyiodides are a class of polyhalogen anions composed entirely of…

Q: 3.4. Propose three alkoxides, which should be as different in structure as possible, that you would…

A: Given structure CpFe(CO)2(OR) We need to explain whether CpFe(CO)2(OR)) is linear or bent at O.

Q: 6. Which structure is not planar? Why? А. В. С. D. O:

A: According to huckel's rule, all aromatic species must be cyclic, planar and contain 4n+2 pi…

Q: The reaction of calcium hydride, CaH2, with water can be characterized as a Lewis acid-base…

A: In the given chemical reaction of calcium hydride with water: The ions are separated as: Here, the…

Q: The space shuttle orbiter utilizes the oxidation of methyl- hydrazine by dinitrogen tetroxide for…

A: Calculate enthalpy of the given reaction by using appendix in the question-

Q: List the individual steps used in constructing a Born–Habercycle for the formation of BaI2 from the…

A: The conversion of solid Barium (Ba) to barium vapor is sublimation as direct conversation of solid…

Q: What is the hybridization of the central atom in the hypophosphite (PO3-2) ion?

A: Hypophosphite formula – (PO2)3- or (H2PO2)-

Q: What is the charge (oxidation state) of the cation in Hg2O?

A: In a neutral compound, the number of positive charges on a cation is equal to the number of negative…

Q: Draw a Lewis electron-dot diagram for the disilicate ion (Si2O9 ). What changes in this structure…

A: Draw and compare Lewis structures for the disilicate ion, the diphosphate ion, and the disulfate…

Q: Explain why SO2 is used as a reducing agent but SO3 is not

A: The process in which a species undergoes the loss of electrons is defined as oxidation, whereas the…

Q: Using an MO energy-level diagram, deterine whether you would expect the O2 molecule to have a lower…

A: Ionisation energy is the amount of energy needed to remove an electron from the atom or the…

Q: For the elements of groups 13 to 17 of the second period, how can they complete their valence layer?…

A: The electrons in the outermost principal energy level of an atom that can participate in formation…

Q: For each of the following molecules, write a Lewis structure, predict the molecular structure…

A: So we’re going to determine Lewis structure, molecular structure ,bond angles, and hydra orbitals…

Q: Discuss the nature of the bonding in the nitrite ion (NO2). Draw the possible Lewis resonance…

A: The resonance structures of nitrite ion, the steric number, and the geometry of the ion should be…

Q: Using Wade's rules, derive the structure of a hypothetical heteroborane with the molecular formula…

A: According to Wade's rule, the structures of heteroboranes are classified on the basis of the…

Q: Hydrogen peroxide can act as either an oxidizing agent or a reducing agent. (a) When H₂O₂ is treated…

A: When H2O2 is treated with aqueous KI, I2 is formed. The oxidation state (O.state) of iodine in KI is…

Q: FH,C OH v.s. H3C 1. Determine, with brief explanation, which of the following is expected to have a…

A: THIS IS A MULTIPART QUESTION,AND AS PER REGULATION I CAN ONLY ANSWER THE FIRST THREE QUESTION IF YOU…

Q: What is the hydrization of the carbon atom in phosgene, Cl2CO? Give a complete description of the σ…

Q: The N20 molecule is linear and polar. a. On the basis of this experimental evidence, which…

A: N2O is a linear and polar molecule.

Q: What kinds of intermolecular interactions would occur in NH3 (1)? What kinds of intermolecular…

Q: The concept of valence-shell electron-pair repulsion (VSEPR) is presented in introductory organic…

A: According to VSPER theory, Regions of electron density around the central atom is four, the…

Q: terms of structure, which of the following does not belong with the rest? Select one: a.NO2‒…

Question

2.10 (a) Construct an MO diagram for the formation of O2;
use only the valence orbitals of the oxygen atoms. (b)
Use the diagram to rationalize the following trend in
0–0 bond distances: O2, 121 pm; [O2]*, 112 pm;
[02]¯, 134 pm; [O2]²¯, 149 pm. (c) Which of these
species are paramagnetic?

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1

Step 2

Step 3

Step 4

Trending now

This is a popular solution!

Step by step

Solved in 4 steps with 1 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

If an element is bonded to 4 other atoms and has a formal charge of +1, what group must the element be in? I know that group 3A atoms are elctron deficient, and that period 3 elements and below, except for group 3A elements like Aluminum, can expand their octet because of their available d-orbital, which may not be relevant to this problem. I don't understand this question, or why the answer would be 5A. Is it because 5A have odd valence electrons, and can form free radicals, like NO?
.For anion NO2-, (a) predict the stereochemistry. Justify your prediction with VSEPR theory and by formal charge; (b) indicate the hybridization appropriate to the stereochemistry; (c) describe the bond character of N-O for the resonance structure.
5b) i) Discuss the bonding and extra.stability of benzene,ii) Using suitable examples, compare the reactivity of benzene and ethane,
In which of these two hydrides:NH3or SbH3,would you expect a greater distortion from the normal tetrahedral bond angle of 109°? And give reason for your answer
The sulfate ion can be represented with four S—O bonds orwith two S—O and two S=O bonds. (a) Which representation is better from the stand point of formal charges? (b) What is theshape of the sulfate ion, and what hybrid orbitals of S are postu-lated for the σ bonding? (c) In view of the answer to part (b),what orbitals of S must be used for the π bonds? What orbitalsof O? (d) Draw a diagram to show how one atomic orbital fromS and one from O overlap to form a π bond.
Account for the following :(a) XeF2has linear structure and not a bent structure.(b) Phosphorus show marked tendency for Catenation.
The existence of compounds of the noble gases was once a great surprise and stimulated a great deal of theoretical work. Sketch the molecular orbital energy level diagram for XeF and deduce its ground-state electron configurations. Is XeF likely to have a shorter or longer bond than XeF+?
High-resolution photoelectron spectroscopy has provided information on the energy levels and bond distance in the ion. Prepare a molecular orbital energy level diagram for this ion Ar2+. How would you expect the bond distance in to compare with 198.8 pm, the bond distance in Cl2
The azide ion ( N3-) is a weakly bound molecular ion. Formulate its MO structure for localized s bonds and delocalized p bonds. Do you expect N3 and N3+o be bound as well? Which of the three species do you expect to beparamagnetic?
How do the acidities of aqueous solutions of Tl2O and Tl2O3 compare with each other? Explain. Please make it clear to read.
It has been suggested that a compound of formulaC12B24N24 might exist and have a structure similar to thatof C60 (buckminsterfullerene).(a) Explain the logic of this suggestion by comparing thenumber of valence electrons in C60 and C12B24N24.(b) Propose the most symmetric pattern of carbon, boron,and nitrogen atoms in C12B24N24 to occupy the 60 atomsites in the buckminsterfullerene structure. Where couldthe double bonds be placed in such a structure?
What is the hybridization of As in AsCl3?