A critical reaction in the production of energy to do work or drive chemical reactions in biological systems is the hydrolysis ofadenosine triphosphate, ATP, to adenosine diphosphate, ADP, as described by the reactionАТР(аq) + H,О() — ADP(aq) + HPО (aq)for which AGixn = -30.5 kJ/mol at 37.0 °C and pH 7.0. Calculate the value of AGrxn in a biological cell in which[ATP] = 5.0 mM, [ADP] = 0.80 mM, and [HPO?-] = 5.0 mM.AGTXN =kJ/molIs the hydrolysis of ATP spontaneous under these conditions?yesno

The given reaction is, ATPaq+H2Ol→ADPaq+HPO42-aq Also given, ∆Grxn°=-30.5 kJ/mol T=37°C=37+273=310K…

A critical reaction in the production of energy to do work or drive chemical reactions in biological systems is the hydrolysis of adenosine triphosphate, ATP, to adenosine diphosphate, ADP, as described by the reaction ATP(aq) + H,O(1) → ADP(aq) + HPO" (aq) for which AGan = -30.5 kJ/mol at 37.0 °C and pH 7.0. Calculate the value of AGxn in a biological cell in which [ATP] = 5.0 mM, [ADP] = 0.80 mM, and [HPO;-] = 5.0 mM. AGxn kJ/mol Is the hydrolysis of ATP spontaneous under these conditions? yes no

A critical reaction in the production of energy to do work or drive chemical reactions in biological systems is the hydrolysis of adenosine triphosphate, ATP, to adenosine diphosphate, ADP, as described by the reaction ATP(aq) + H,O(1) → ADP(aq) + HPO" (aq) for which AGan = -30.5 kJ/mol at 37.0 °C and pH 7.0. Calculate the value of AGxn in a biological cell in which [ATP] = 5.0 mM, [ADP] = 0.80 mM, and [HPO;-] = 5.0 mM. AGxn kJ/mol Is the hydrolysis of ATP spontaneous under these conditions? yes no

Chemistry for Engineering Students

4th Edition

ISBN:9781337398909

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter10: Entropy And The Second Law Of Thermodynamics

Section: Chapter Questions

Problem 10.86PAE: The enthalpy of vaporization for water is 40.65 kJ mol-1. As a design engineer for a project in a...

See similar textbooks

Similar questions

Benzoic acid, C6H5COOH, is a common standard used in bomb calorimeters, which maintain a constant volume. If 1.20 g of benzoic acid gives off 31, 723 J of energy when burned in the presence of excess oxygen and in a water bath having a temperature of 24.6 C, calculate q, w, H, and U for the reaction.
When 1.000 g of ethylene glycol, C2H6O2, is burned at 25C and 1.00 atmosphere pressure, H2O(l) and CO2(g) are formed with the evolution of 19.18 kJ of heat. a Calculate the molar enthalpy of formation of ethylene glycol. (It will be necessary to use data from Appendix C.) b Gf of ethylene glycol is 322.5 kJ/mol. What is G for the combustion of 1 mol ethylene glycol? c What is S for the combustion of 1 mol ethylene glycol?
Would the amount of heat absorbed by the dissolution in Example 5.6 appear greater, lesser, or remain the same if the heat capacity of the calorimeter were taken into account? Explain your answer.
For the reaction BaCO3(s) BaO(s) + CO2(g), rG = +219.7 kJ/mol-rxn. Using this value and other data available in Appendix L, calculate the value of fG for BaCO3(s).
When one mol of KOH is neutralized by sulfuric acid, q=56 kJ. (This is called the heat of neutralization.) At 23.7C, 25.0 mL of 0.475 M H2SO4 is neutralized by 0.613 M KOH in a coffee-cup calorimeter. Assume that the specific heat of all solutions is 4.18J/gC, that the density of all solutions is 1.00 g/mL, and that volumes are additive. (a) How many mL of KOH is required to neutralize H2SO4? (b) What is the final temperature of the solution?
Calculate the standard Gibbs free-energy change when SO3 forms from SO2 and O2 at 298 K. Why is sulfur trioxide an important substance to study? (Hint: What happens when it combines with water?)
When 1.000 g of gaseous butane, C4H10, is burned at 25C and 1.00 atm pressure, H2O(l) and CO2(g) are formed with the evolution of 49.50 kJ of heat. a Calculate the molar enthalpy of formation of butane. (Use enthalpy of formation data for H2O and CO2.) b Gf of butane is 17.2 kJ/mol. What is G for the combustion of 1 mol butane? c From a and b, calculate S for the combustion of 1 mol butane.
Another step in the metabolism of glucose, which occurs after the formation of glucose6-phosphate, is the conversion of fructose6-phosphate to fructose1,6-bisphosphate(bis meanstwo): Fructose6-phosphate(aq) + H2PO4(aq) fructose l,6-bisphosphate(aq) + H2O() + H+(aq) (a) This reaction has a Gibbs free energy change of +16.7 kJ/mol of fructose6-phosphate. Is it endergonic or exergonic? (b) Write the equation for the formation of 1 mol ADP fromATR for which rG = 30.5 kJ/mol. (c) Couple these two reactions to get an exergonic process;write its overall chemical equation, and calculate theGibbs free energy change.
A 220-ft3 sample of gas at standard temperature and pressure is compressed into a cylinder, where it exerts pressure of 2000 psi. Calculate the work (in J) performed when this gas expands isothermally against an opposing pressure of 1.0 atm. (The amount of work that can be done is equivalent to the destructive force of about 1/4 lb of dynamite, giving you an idea of how potentially destructive compressed gas cylinders can be if improperly handled!)
The enthalpy of vaporization for water is 40.65 kJ mol-1. As a design engineer for a project in a desert climate, you are exploring the option of using evaporative cooling. (a) If the air has an average volumetric heat capacity of 0.00130 J cm-3 K-1, what is the minimum mass of water that would need to evaporate in order to cool a 5 m? 5 m room with a 3 m ceiling by 5°F using this method? (b) Is this a spontaneous or nonspontaneous process?