A first row transition metal ion, M³+, was allowed to react with two sets of monodentate ligands, D and E. The complex [MD]³+ was found to be highly paramagnetic while the complex [ME6]³- was weakly paramagnetic. Further studies on [ME6]³- revealed the weak paramagnetism of the complex arises from the presence of a single unpaired electron. From these pieces of information, answer the following: Hybridization of M³+ in [MD6]³+ (No need to write the number of orbitals as superscripts, e.g., sp3): Hybridization of M³+ in [ME6]³- (No need to write the number of orbitals as superscripts, e.g., sp3): Identity of M (No need to write the charge; just write the symbol, e.g. Au): type your answer... type your answer... type your answer.... Identity of ligand D: choose your answer... choose your answer... carbon monoxide water ethylenediamine (en) Identity of ligand E: choose your answer... 16 choose your answer... oxalate bromide cyanide

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter21: Transition Metals And Coordination Chemistry
Section: Chapter Questions
Problem 108IP: a. In the absorption spectrum of the complex ion Cr(NCS)63, there is a band corresponding to the...
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A first row transition metal ion, M³+, was allowed to react with two sets of monodentate ligands, D and E. The complex [MD]³+ was found to be highly paramagnetic
while the complex [ME6]³ was weakly paramagnetic. Further studies on [ME6]³ revealed the weak paramagnetism of the complex arises from the presence of a single
unpaired electron. From these pieces of information, answer the following:
Hybridization of M³+ in [MD6]³+ (No need to write the number of orbitals as superscripts, e.g., sp3):
type your answer...
type your answer...
Hybridization of M³+ in [ME6]³- (No need to write the number of orbitals as superscripts, e.g., sp3):
Identity of M (No need to write the charge; just write the symbol, e.g. Au): type your answer...
Identity of ligand D:
choose your answer...
choose your answer...
carbon monoxide
water
ethylenediamine (en)
16
Identity of ligand E:
choose your answer...
choose your answer...
oxalate
bromide
cyanide
Transcribed Image Text:16 A first row transition metal ion, M³+, was allowed to react with two sets of monodentate ligands, D and E. The complex [MD]³+ was found to be highly paramagnetic while the complex [ME6]³ was weakly paramagnetic. Further studies on [ME6]³ revealed the weak paramagnetism of the complex arises from the presence of a single unpaired electron. From these pieces of information, answer the following: Hybridization of M³+ in [MD6]³+ (No need to write the number of orbitals as superscripts, e.g., sp3): type your answer... type your answer... Hybridization of M³+ in [ME6]³- (No need to write the number of orbitals as superscripts, e.g., sp3): Identity of M (No need to write the charge; just write the symbol, e.g. Au): type your answer... Identity of ligand D: choose your answer... choose your answer... carbon monoxide water ethylenediamine (en) 16 Identity of ligand E: choose your answer... choose your answer... oxalate bromide cyanide
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