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(a) Given the ionic radii, Cst = 1.67Å, CI = 1.81Å, and the Madelung constant M(CSCI) = 1.763, determine to the best of your ability the molar Crystal energy (AEcryst) for CsCl. (b) Not given additional data, do you expect the value obtained to be larger or smaller than theoretical, and by how many percent do you anticipate to be off?

(a) Given the ionic radii, Cst = 1.67Å, CI = 1.81Å, and the Madelung constant M(CSCI) = 1.763, determine to the best of your ability the molar Crystal energy (AEcryst) for CsCl. (b) Not given additional data, do you expect the value obtained to be larger or smaller than theoretical, and by how many percent do you anticipate to be off?

Chemistry: The Molecular Science
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter19: The Chemistry Of The Main-group Elements
Section: Chapter Questions
Problem 96QRT: Use a Born-Haber cycle (Sec. 5-13) to calculate the lattice energy of MgF2 using these thermodynamic...
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(a) Given the ionic radii, Cst = 1.67Å, CI = 1.81Å, and the Madelung constant M(CSCI) = 1.763, determine to the best of your ability the molar Crystal energy (AEcryst) for CsCl. (b) Not given additional data, do you expect the value obtained to be larger or smaller than theoretical, and by how many percent do you anticipate to be off?
Transcribed Image Text:(a) Given the ionic radii, Cst = 1.67Å, CI = 1.81Å, and the Madelung constant M(CSCI) = 1.763, determine to the best of your ability the molar Crystal energy (AEcryst) for CsCl. (b) Not given additional data, do you expect the value obtained to be larger or smaller than theoretical, and by how many percent do you anticipate to be off?
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