(a) Ignoring stereoisomers, what two allylic hydroperoxides are formed by the oxidation of 1-hexene with O,? (b) Draw a stepwise mechanism that shows how these hydroperoxides are formed.
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- Draw the simplified curved arrow mechanism for the reaction of pentan-2-one and CH3Li to give the major productDraw the mechanism of the following reactions using curved arrows. For reaction b,show the stereochemistry of the productDraw the products of attached reaction, and indicate the stereochemistrywhere appropriate.
- a. What alkene would give only a ketone with three carbons as a product of oxidative cleavage? b. What alkenes would give only an aldehyde with four carbons as a product of oxidative cleavage?Provide a curved-arrow mechanism for the following reaction. In a few words, explain the regiochemistry of the OH in the product (is this conjugate or direct addition, and what causes the reaction to proceed via that addition mechanism).Draw all products, including stereoisomers, in attached reaction.
- Draw all stereoisomers formed in the attached two-step reactionsequence.Give the reults of a mono-hydroxylation and N-dealkylation of the structureA. Arrange the following radicals in order of decreasing rate of bromination. Justify your answer. B. Trehalose and isomaltose are both dimers of glucose. However, they have considerablydifferent reactivities. Concisely explain why these differences are observed. -Isomaltose is a reducing sugar while trehalose is not.-Trehalose is very resistant to acid hydrolysis while isomaltose can be acid-hydrolyzed withease.
- Please help with the following: Draw a detailed step-wise mechanism for the following reaction. Be sure to show all steps, intermediates, formal charges, and show the movement of electrons with curved arrows.Draw the curved arrow mechanisms to obtain the products and comment on the selecitivityCan you further explain c & d? I'm confused with both as those were the only ones I got wrong. First for c, why is there a reaction on the most substituted alkene vs the terminal alkene? Secondly for d, why did both OH groups experience a reaction vs just the attached to a primary carbon. Thank youagain for the help!