A mass spectrometer is a tool used to determine accurately the mass of individual ionized atoms or molecules, or to separate atoms or molecules that have similar but slightly different masses. For example, you can deduce the age of a small sample of cloth from an ancient tomb, by using a mass spectrometer to determine the relative abundances of carbon-14 (whose nucleus contains 6 protons and 8 neutrons) and carbon-12 (the most common isotope, whose nucleus contains 6 protons and 6 neutrons). In organic material the ratio of 14C to 12c depends on how old the material is, which is the b for "carbon-14 dating." 14C is continually produced in the upper atmosphere by nuclear reactions caused by "cosmic rays" (high-energy charged particles from outer space, mainly protons), and 14C is radioactive with a half-life of 5700 years. When a cotton plant is growing, some of the CO2 it extracts fro the air to build tissue contains 14C which has diffused down from the upper atmosphere. But after the cotton has been harvested there is no further intake of 1"C from the air, and the cosmic rays that create 1"C in the upper atmosphere can't penetrate the atmosphere and reach the cloth. So the amount 140 cotton cloth continually decreases with time, while the amount of non-radioactive 12c remains constant. Here is a particular kind of mass spectrometer (see the figure). Carbon from the sample is ionized in the ion source at the left. The resulting singly ionized 12ct and 14c+ ions have negligibly small initial velocities (and can be considered to be at rest). They are accelerated through the potential difference They then enter a region where the magnetic field has a fixed magnitude B = 0.17 T. The ions pass through electric deflection plates that are 1 cm apart and have a potential difference AV2 that is adjusted so that the electric deflection and the magnetic deflection cancel each other for a particular isotope isotope goes straight through, and the other isotope is deflected and misses the entrance to the next section of the spectrometer. The distance from the entrance to the fixed ion detector is a distance of w = 24 cm. There are controls that let you vary the accelerating potential AV, and the deflection poter AVz in order that only 12ct or 14c* ions go all the way through the system and reach the detector. You count each kind of ion for fixed times and thus determine the relative abundances. The various deflections insure that you count only the desired type of ion for a particular setting of the two voltages. Accelerating

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Mass spectrometer
A mass spectrometer is a tool used to determine accurately the mass of individual ionized atoms or molecules, or to separate atoms or molecules that have similar but slightly different masses. For example, you can deduce the age of a small sample of cloth from an ancient tomb, by using a mass
spectrometer to determine the relative abundances of carbon-14 (whose nucleus contains 6 protons and 8 neutrons) and carbon-12 (the most common isotope, whose nucleus contains 6 protons and 6 neutrons). In organic material the ratio of 14C to 12C depends on how old the material is, which is the ba
for "carbon-14 dating." 14C is continually produced in the upper atmosphere by nuclear reactions caused by "cosmic rays" (high-energy charged particles from outer space, mainly protons), and 14C is radioactive with a half-life of 5700 years. When a cotton plant is growing, some of the CO2 it extracts from
the air to build tissue contains 14C which has diffused down from the upper atmosphere. But after the cotton has been harvested there is no further intake of 14C from the air, and the cosmic rays that create 14C in the upper atmosphere can't penetrate the atmosphere and reach the cloth. So the amount o
14C in cotton cloth continually decreases with time, while the amount of non-radioactive 12c remains constant.
Here is a particular kind of mass spectrometer (see the figure). Carbon from the sample is ionized in the ion source at the left. The resulting singly ionized 12c+ and 14c+ ions have negligibly small initial velocities (and can be considered to be at rest). They are accelerated through the potential difference 4
They then enter a region where the magnetic field has a fixed magnitude B = 0.17 T. The ions pass through electric deflection plates that are 1 cm apart and have a potential difference AV2 that is adjusted so that the electric deflection and the magnetic deflection cancel each other for a particular isotope:
isotope goes straight through, and the other isotope is deflected and misses the entrance to the next section of the spectrometer. The distance from the entrance to the fixed ion detector is a distance of w = 24 cm. There are controls that let you vary the accelerating potential AV1 and the deflection potent
AV2 in order that only 12c+ or 14c+ ions go all the way through the system and reach the detector. You count each kind of ion for fixed times and thus determine the relative abundances. The various deflections insure that you count only the desired type of ion for a particular setting of the two voltages.
Accelerating
plates; AV1
IonE
detector
Deflection
plates; AV2
IonE
source
Other isotope
is deflected
nonzero B
throughout this region
(a) Which accelerating plate is positive?
O left
O right
Which deflection plate is positive?
O bottom
O top
What is the direction of the magnetic field inside the spectrometer?
O into page
O out of page
(b) Determine the appropriate numerical values of AV and AV2 for 12c. Carry out your intermediate calculations algebraically, so that you can use the algebraic results in the next part.
AV1
V
Δν
V
(c) Determine the appropriate numerical values of AV1 and AV2 for 14c.
Av1 =
V
AV2 =
V
Transcribed Image Text:Mass spectrometer A mass spectrometer is a tool used to determine accurately the mass of individual ionized atoms or molecules, or to separate atoms or molecules that have similar but slightly different masses. For example, you can deduce the age of a small sample of cloth from an ancient tomb, by using a mass spectrometer to determine the relative abundances of carbon-14 (whose nucleus contains 6 protons and 8 neutrons) and carbon-12 (the most common isotope, whose nucleus contains 6 protons and 6 neutrons). In organic material the ratio of 14C to 12C depends on how old the material is, which is the ba for "carbon-14 dating." 14C is continually produced in the upper atmosphere by nuclear reactions caused by "cosmic rays" (high-energy charged particles from outer space, mainly protons), and 14C is radioactive with a half-life of 5700 years. When a cotton plant is growing, some of the CO2 it extracts from the air to build tissue contains 14C which has diffused down from the upper atmosphere. But after the cotton has been harvested there is no further intake of 14C from the air, and the cosmic rays that create 14C in the upper atmosphere can't penetrate the atmosphere and reach the cloth. So the amount o 14C in cotton cloth continually decreases with time, while the amount of non-radioactive 12c remains constant. Here is a particular kind of mass spectrometer (see the figure). Carbon from the sample is ionized in the ion source at the left. The resulting singly ionized 12c+ and 14c+ ions have negligibly small initial velocities (and can be considered to be at rest). They are accelerated through the potential difference 4 They then enter a region where the magnetic field has a fixed magnitude B = 0.17 T. The ions pass through electric deflection plates that are 1 cm apart and have a potential difference AV2 that is adjusted so that the electric deflection and the magnetic deflection cancel each other for a particular isotope: isotope goes straight through, and the other isotope is deflected and misses the entrance to the next section of the spectrometer. The distance from the entrance to the fixed ion detector is a distance of w = 24 cm. There are controls that let you vary the accelerating potential AV1 and the deflection potent AV2 in order that only 12c+ or 14c+ ions go all the way through the system and reach the detector. You count each kind of ion for fixed times and thus determine the relative abundances. The various deflections insure that you count only the desired type of ion for a particular setting of the two voltages. Accelerating plates; AV1 IonE detector Deflection plates; AV2 IonE source Other isotope is deflected nonzero B throughout this region (a) Which accelerating plate is positive? O left O right Which deflection plate is positive? O bottom O top What is the direction of the magnetic field inside the spectrometer? O into page O out of page (b) Determine the appropriate numerical values of AV and AV2 for 12c. Carry out your intermediate calculations algebraically, so that you can use the algebraic results in the next part. AV1 V Δν V (c) Determine the appropriate numerical values of AV1 and AV2 for 14c. Av1 = V AV2 = V
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