A mixture of three compounds, A, B, and C is to be separated and purified by crystallization Their solubilities in g/100mL ethanol are given below: Solvent A Cold 1.05 5.60 4.20 Hot 20.5 2.3 3.50 a. If a mixture containing 4.0 g of each A, B and C is recrystallized from 100 mL ethanol, which compound would be obtained pure? b. If the filtrate from (a) is evaporated to 50 mL, which of the compound(s) will separate upon cooling? What is its purity?

A mixture of three compounds, A, B, and C is to be separated and purified by crystallization Their solubilities in g/100mL ethanol are given below: Solvent A Cold 1.05 5.60 4.20 Hot 20.5 2.3 3.50 a. If a mixture containing 4.0 g of each A, B and C is recrystallized from 100 mL ethanol, which compound would be obtained pure? b. If the filtrate from (a) is evaporated to 50 mL, which of the compound(s) will separate upon cooling? What is its purity?

Macroscale and Microscale Organic Experiments

7th Edition

ISBN:9781305577190

Author:Kenneth L. Williamson, Katherine M. Masters

Publisher:Kenneth L. Williamson, Katherine M. Masters

Chapter7: Extraction

Section: Chapter Questions

Problem 1Q

See similar textbooks

Similar questions

(1a) Pure benzophenane freezes at 66.6 °C. A solution of 7.75 g of biphenyl (C12H10; molar mass = 154.2g/mol) plus 200.08 g of benzophenane froze at 59.9 °C. Calculate the Kf of benzophenane in °C*kg/mol. (b) An unknown solution with possible cations (Ag+, Hg22+, Pb2+) is treated with 6M HCl and a white precipitate forms. Hot water is added to the precipitate, and a white solid remains after filtration. The white solid is treated with aqueous NH3, and the precipitate turns grey or black. The resulting solution is treated with HNO3 and no precipitate forms. What cations can you determine to be present, absent or maybe present? Explain your reason
The Ksp values of two solid carbonates, A2CO3 and BCO3, were determined by preparing 250.0-mL saturated aqueous solutions of both solids and then determining the concentration of carbonate by titrating it with 0.01023 M HCl up to methyl orange endpoint. Solutions of A2CO3 and BCO3 required 6.184 mL and 3.456 mL of the titrant, respectively. a. What are the concentration of carbonate in each of the saturated solutions of A2CO3and BCO3?b. What are the Ksp values of A2CO3 and BCO3? c. If 8.721 mg A2CO3 and 1.769 mg BCO3 were needed to prepare the saturated solutions, what are the identity of A2CO3and BCO3 ?Hint: deduct the molecular weight of carbonated. Instead of distilled water, 250.0 mL of 0.10 M ANO3 was used to prepare a saturatedsolution of A2CO3 while 250.0 mL of 0.10 M B(NO3)2 was used for BCO3. Which will have a higher solubility?
The Ksp values of two solid carbonates, A2CO3 and BCO3, were determined by preparing 250.0-mL saturated aqueous solutions of both solids and then determining the concentration of carbonate by titrating it with 0.01023 M HCl up to methyl orange endpoint. Solutions of A2CO3 and BCO3 required 6.184 mL and 3.456 mL of the titrant, respectively.d. Instead of distilled water, 250.0 mL of 0.10 M ANO3 was used to prepare a saturatedsolution of A2CO3 while 250.0 mL of 0.10 M B(NO3)2 was used for BCO3. Which will have a higher solubility?
If the solubility of a compound A in ether is 30g/100 ml, and the solubility of A in water is 15 g /100 ml. a) If 100 ml of aqueous solution of 3g of A are extracted twice with 100 ml ether. How much A total is extracted? b) How much A would be extracted if only one extraction, but with a volume of 200 ml of ether were extracted? c) What is your conclusion from the amount of A extracted in problems a and b above?
A worker in a dye factory accidentally mixed the compound labeling and you were tasked in identifying one of the dyes. One solution states it contained a saturated 0.25302% dye by mass in ethanol solvent. By measuring its weight and volume, the density of the solution was determined to be 0.79046 g/mL. The solution was further analyzed and determined to have a concentration of 0.00239266 M pink dye. What is the molecular weight of the dye? Hint: %w/v
You were given a mixture of two miscible solvent A and B that you are tasked to separate. You know that solvent A has a boiling point of 49 oC while solvent B has a boiling point of 174 oC. Which of the listed method would overall be the most efficient? Fractional distillation Recrystallization Solid-liquid extraction Liquid-liquid extraction Simple distillation Acid-Base extraction
Transfer 3-4 drops or a pinch of the test compound (Acetanilide) to 3 ml of the solvents, 5% NaOH and 5% NaHCO3 Shake the mixture thoroughly. The time required for the solute to dissolve in the solvent should not be more than 2 minutes. Indicate with (+) or (-) if the test compound is soluble or insoluble in the solvent. What is the theoretical solubility of Acetanilide in 5% NaOH? _______ What is the theoretical solubility of Acetanilide in 5% NaHCO3? _______
A 25 mL liquid bleach sample is diluted with water to 1000 mL in a bubble gel. 25 mL of the diluted sample is transferred to the flask with a pipette, excess KI is added to it, and thus OCl- ion turns into Cl- ion and I2 is formed. The released iodine is titrated with 0.09892 M Na2S2O3 using the starch reagent, and 8.96 mL is required for the endpoint. Find the % NaOCl (w/v; w/v) in the bleach sample. (Na=23 g/mol, O= 16 g/mol, Cl = 35.44 g/mol) (Warning: solving the necessary reaction equations by writing is necessary to see the stoichiometric relationship) A. 0.132% B. 0.264% C. 5.28% D. 10.56%
The Ksp of Cu3 (AsO4)2 at 25^0C is 7.6×10^-36. What is the molar solubility of Cu3 (AsO4)2 in water at 25^0C?
You are asked to make the compound [Ni(en)3]SO4. - By using 2.611 grams of NiSO4*6H2O (s) you dissolve the sample in deionized water completely. - You then add 10ml of 25% en into the solution and mix until a single product forms - When the addition of the en is complete, you then add 15ml of ethanol and mix. - using a bench vaccine and Buchner funnel, you filter the precipitate while carefully breaking up the solid until powder form. - the product is the washed with 15ml of ethanol and 15ml of acetone. Powder the solid and leave to dry Which is the limiting reagent? Write a balanced chemical equation for the reaction. How many miles of the product can you theoretically prepare?
One litre of a saturated aqueous solution of Ag2SO4 (MW = 311.79 g mol- 1) at 25 °C is evaporated to dryness. 4.844 g of Ag2SO4 residue was produced. What is the solubility product (Ksp)?
The separation and purification processes given below and the method used against them are given. Which or which of these pairings are correct? I. Brewing of tea - ExtractionII. Purification of water impurities - ChromatographyIII. Separating olive pomace from olive oil while producing olive oil-DecantationIV.Petroleum fractions obtaining - Ordinary distillationV. Obtaining essential oils and using them in perfume making - Water-steam distillationA. I, II, III, IVB. I, II, III, IV, VC. I, IV, VD. I, II, III, VE. I, II, V