A ОА B CH₂OH Br2 OH "OH 1.03 2. DMS KMnO4, NaOH cold HI mCPBA 1.0504 2. H2Oz 1.03 2. (CH3)2S 17 16 15 14 CH,COJH (peroxyacid) "OH 13 OH B H₂ Pd or Pt (catalyst) HBr 201 2 12 11 10 1. MCPBA 2. О Pd or Ni (catalyst) D2 (deuterium) EtOH Br₂ OH dou don dan dan do OH "OH 'OH "OH OH OH BH₂ THF "OH HBr ROOR (peroxide) H,20 H2SO4 HCI C 1. BH₂ THF 2. H2NaOH Br₂ Br₂ H2O D OH ба OH OH YOH

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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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14.

Subject  :- Chemistry 

Please predict the products for each of the following reactions.
Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both).
If a mixture of enantiomers is formed, please draw all the enantiomers.
A
„OH
Jon
OH
+
O A
B
D
OH
"OH
CH₂OH
Bra
1.03
2. DMS
KMnO4, NaOH
cold
HI
mCPBA
1. Os04
2. H₂O₂
16
15
..OH
18
CH₂CO3H
(peroxyacid)
OH
"OH
19 20
14
B
MCPBA
Pd or Pt (catalyst)
· H3O+
23
12 11 10
Pd or Ni (catalven
i (catalyst)
D₂ (deuterium)
EtOH
OH
"OH
OH
OH
Br
BH3 THF
HBr
ROOR (peroxide)
H₂O
H₂SO4
HCI
C
1. BH 3 THF
2. H₂O₂, NaOH
Br₂
Br₂
H₂O
,,OH
OH
Ion Iom
'OH
OH
OH
D
'OH
OH
OH
Transcribed Image Text:Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. A „OH Jon OH + O A B D OH "OH CH₂OH Bra 1.03 2. DMS KMnO4, NaOH cold HI mCPBA 1. Os04 2. H₂O₂ 16 15 ..OH 18 CH₂CO3H (peroxyacid) OH "OH 19 20 14 B MCPBA Pd or Pt (catalyst) · H3O+ 23 12 11 10 Pd or Ni (catalven i (catalyst) D₂ (deuterium) EtOH OH "OH OH OH Br BH3 THF HBr ROOR (peroxide) H₂O H₂SO4 HCI C 1. BH 3 THF 2. H₂O₂, NaOH Br₂ Br₂ H₂O ,,OH OH Ion Iom 'OH OH OH D 'OH OH OH
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