a oe 2.2 Introduction to Organic Chemistry Draw condensed structures from the following molecular formulae. In the case of resonance, draw all plausible structures and denote the most stable hybrid. (a) N3 (b) (CH3)3COH (c) (CH3)2NNO2 (d) (CH3)2CHNH2 (e) H2CNN (f) H2N2
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- Is the following compound aromatic? Describe comprehensivelyThe global consumption of synthetic dyes is increasing due to increase in demand invarious processing/manufacturing industries. Analyze why among the large number of organic molecules, only relatively few moleculesare considered as dyes. Select any one dye which is used in industry and give justificationof type of the dye, its application in the industry and related reactions.Biphenyl has the following structure.(a) Is biphenyl a (fused) polynuclear aromatic hydrocarbon?(b) How many pi electrons are there in the two aromatic rings of biphenyl? How does this number compare with that for naphthalene?
- 1. What is resonance theory? State five conclusionstgan can be drawn from the theory. 2.What factors confer aromaticity to an organic molecule. 3. What are the various ways by which alkenes can be synthesized. 4. State the two main experiment that were used to establish the extra stability of the benzene molecule.Write chemical structures for compounds A through D in the following sequence of reac- tions. Compounds A and C are alcohols, one of which is cyclicQuestion:What is the significance of the LUMO (Lowest Unoccupied Molecular Orbital) in organic chemistry, and how does it contribute to chemical reactions?
- rank the set of compounds and explain brieflyAn important class of substances in organic chemistry are the aliphatic and aromatic hydrocarbons and theirssubstituted derivatives. In this assignment: Remember to take any isomerism and the VSEPR principles into account A) Study the series of ring structures a – d in the figure above. Fill in the IUPAC names for the rings a - d.Are any of these rings aromatic? Can you say something about what aromaticity means chemically? B) Suggest probable IUPAC names of the following substituted hydrocarbon compounds which areshown in skeletal structure: See image bFUNCTIONAL GROUPS The research team on Natural Products Chemistry from De La Salle University-Dasmariñas under Mr. Gab has discovered a novel compound from an endemic Philippine nudibranch, Chromodoris cavitensis, whichinhabits the coral reef system near Caylabne Bay in Ternate, Cavite. Exhaustive analysis has revealed acomplex structure as shown below which they aptly named as “chromocavitenin”. Initial tests revealed that thiscompound has potent anti-carcinogenic properties. Encircle and identify the 13 distinct functional groups that arepresent in chromocavitenin.
- Naphthalene is a white volatile, solid polycyclic hydrocarbon used in moth balls and repellents. Looking at the structure of naphthalene given below, determine if it is aromatic or not. Please explain the reasoningThe calicene molecule has a different dipolar moment of 0 and also thedipole points to the larger ring. Draw a structure resonance where you can see that distribution of loads and using the concept of aromaticity and resonance structures, explain why the moment dipolarit's different from zeroThiols are sulfur containing organic compounds. Allyl mercaptan is a small molecule from garlic and responsible for “garlic breath”. Its formula is C3H6S. It has been shown to be the most effective HDAC (Histone deacetylase inhibitors) inhibitor of known garlic-derived organosulfur compounds and their metabolites. Draw all possible isomers with formula C3H6S. Define among the molecules which could be optically active. Which of molecule is allyl mercaptan?