A sample of water from a river was analyzed by titrating a 125 mL aliquot with 0.0210 M EDTA, consuming 22.52 mL. Express the hardness of the water in ppm of CaCO3.
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A sample of water from a river was analyzed by titrating a 125 mL aliquot with 0.0210 M EDTA, consuming 22.52 mL. Express the hardness of the water in ppm of CaCO3.
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- An EDTA solution prepared from its disodium salt was standardized using 0.250-g primary standard CaCO3 (MW=100.087) and consumed 28.50 mL of the solution. The standard solution was used to determine the hardness of a 2.0 L sample of mineral water, which required 35.57 mL EDTA solution. Express the analysis in terms of ppm CaCO3Five white, 500-mg uncoated ascorbic acid (AA) tablets with an average weight of 0.6100-g were pulverized in a mortar. A sample of the powdered ascorbic acid weighing 0.4610-g was placed in an iodine flask and was dissolved in 50-mL H2SO4 then 5-g of KBr was added to the resulting solution. The solution was titrated with 46.73-mL of 0.0152 M STD. KBrO3 to reach a faint yellow endpoint then 3-g KI and 5-mL Starch TS. The blue color solution is then titrated with 2.78-mL of 0.1047 M STD. Na2S2O3 to reach the disappearance of the blue iodostarch complex. MW: KBrO3 = 167.0 ; KIO3 = 214.0 ; Na2S2O3 = 158.11 ; C6H8O6 = 176.12 Compute the milligrams of pure AA per tablet from the assay. None of the choices 349.7 mg 264.3 mg 462.7 mgIf you titrate 50 mL of a sample with 0.06 N EDTA and the titration takes 12.4 mL of EDTA to reach the endpoint, what is the hardness of the sample in ppm as CaCO3?Identify the nature of the water sample from the hardness value.
- In the determination of water hardness by volumetry, AEDT is used. If the volume of 0.01 M EDTA used to titrate 100 mL of sample was 20 mL, calculate the total hardness expressed in mg/L of CaCO3.Consider the titration illustrated in Figure 8.] Anhydrous sodium carbonate (Na₂CO₃) is a primary standard. When 0.364 grams of the substance is placed in a conical flask, then 20.00 cm³ of sulphuric acid (H₂SO₄) solution is required to reach the end point of the titration. What is the concentration in mol·dm⁻³ of the sulphuric acid solution? [Give the answer to 3 decimal places. Do not type in the unit. Use a decimal point.] *If a 35.0-mL water sample required 10.25 mL of 0.0150 M EDTA solution to reach equivalence point, what’s the hardness of the water sample in ppm CaCO3 (FW 100.1 g/mol)?
- 100 mL tap water is titrated with 20 mL of 0.02 M EDTA solution to determine the hardness of the water. The second 100 mL tap water is precipitated as CaC2O4 and removed by filtration and the filtrate is titrated with 8.0 mL of the same EDTA solution. What are the concentrations (as ppm) of Ca2+ (40.078 g/mol) and Mg2+ (24.305 g/mol) ions in the water? 2) 10 g of a solution, containing one or more of NaOH, Na3PO4, Na2HPO4, NaH2PO4, H3PO4 and HCl substances, is titrated with 1.0 M NaOH using the phenolphthalein indicator and 34.5 mL NaOH is used. Another 10 g mixture was titrated to reach the bromocresol green end point and 20.50 mL NaOH is used. What is the composition of the solution? What are the percentages of the species(H:1.0078, O:15.99, Na: 22.98, P:30.974, Cl:35.453)?25.0 cm3 of sodium hydroxide solution is tritrated against 0.200 mol dm–3 hydrochloric acid until the indicator just changes colour. 27.5 cm3 of the acid are required to reach the end point.Which of the following pieces of apparatus should be used to transfer 25.0 cm3 of the sodium hydroxide solution?a. Burette b. Pipette c. Measuring cyclinder d. Volumetric flaskAn impure sample of calcium carbonate with a mass of 7.95 g was reacted with 50.00 cm3 of 1.00 mol dm hydrochloric acid (an excess). The resulling solution was transferred to a volumetric flask and titrated with 11.10cm3 of 0.300 mol dm-3 sodium hydroxide solution. Determine the percentage purity by mass of the calcium carbonate sample.CaCO3 + HCl -> CaCl2 + H2O + CO2 HCl + NaOH -> NaCl +H2O a. Determine how many moles of hydrochloric acid were used.b. Determine how many moles of excess HCI was titratedc. Determine how much in moles calcium carbonate present in the sample.d. Calculate the mass of calcium carbonate presente. Determine the percentwge calcium carbonate is in the sample.
- What is the mass of pure dry CaCO3 (MW: 100.0869 g/mol) standard used in the standardization of EDTA solution? Assume that 1.758 M EDTA solution was computed based on the titration of CaCO3 standard. The volume of titrant needed to reach the endpoint was 35.00 mL. Ca2+ + Y4- → CaY2- 0.1500 g 5.630 g 6.158 g 0.6158 gA 0.1093-g sample of impure Na2CO3 was analyzed by the Volhard method. After adding 50.00 mL of 0.06911 M AgNO3, the sample was back-titrated with 0.05781 M KSCN, requiring 27.36 mL to reach the endpoint. Report the purity of the Na2CO3 sample. [Ans. 90.9 % (w /w )]Determine the total hardness of water (ppm CaCO3; MM: 100.09 g/mole) if 100.0mL sample of drinking water required 38.41mL of 4.65 x 10-3 M EDTA for titration. 179 ppm CaCO3 357 ppm CaCO3 452 ppm CaCO3 733 ppm CaCO3
