What is the principle behind the Markovnikov's rule in the addition of HX (where X is a halogen) to an alkene, and what is the exception to this rule?

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter8: Addition Via Carbocation
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Question: What is the principle behind the Markovnikov's rule in the addition of HX (where X is a halogen) to an alkene, and what is the exception to this rule?

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