A saturated silver carbonate solution (1.0 L) is prepared at 5 °C and filtered to separate the undissolved phase. The filtrate is treated at 25 °C with hydrochloric acid, whereby the carbonate ions decompose and carbon dioxide is formed. The measurement shows that the level of carbon dioxide above the reaction vessel is 600 ppm. All carbon dioxide gas formed is collected in a test tube with a volume of 19 mL, and at 25 °C the pressure is measured to be 114 mmHg. Calculate Ksp for silver carbonate at 5 °C.
A saturated silver carbonate solution (1.0 L) is prepared at 5 °C and filtered to separate the undissolved phase. The filtrate is treated at 25 °C with hydrochloric acid, whereby the carbonate ions decompose and carbon dioxide is formed. The measurement shows that the level of carbon dioxide above the reaction vessel is 600 ppm. All carbon dioxide gas formed is collected in a test tube with a volume of 19 mL, and at 25 °C the pressure is measured to be 114 mmHg. Calculate Ksp for silver carbonate at 5 °C.
Chapter13: Titrations In Analytical Chemistry
Section: Chapter Questions
Problem 13.5QAP
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Question
A saturated silver carbonate solution (1.0 L) is prepared
at 5 °C and filtered to separate the undissolved phase. The filtrate is treated at 25 °C with
hydrochloric acid, whereby the carbonate ions decompose and carbon dioxide is formed. The measurement shows that
the level of carbon dioxide above the reaction vessel is 600 ppm. All carbon dioxide gas formed is collected in
a test tube with a volume of 19 mL, and at 25 °C the pressure is measured to be 114 mmHg. Calculate
Ksp for silver carbonate at 5 °C.
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