A solution of Cu* is undergoing a redox titration by the addition of Ce**. The standard reduction half-reactions and potentials are given. Ce* +e=Ce* E = +1.72 V Cu2+ +e Cu* E = +0.161 V The table shows the properties of four redox indicators. Color Indicator Oxidized Reduced E" (V) yellow-green 5,6-dimethylphenanthroline (Fe complex) indigotrisulfonic acid phenosafranine red +0.97 blue colorless +0.33 red colorless +0.28 viologen colorless blue -0.43 Select a suitable indicator to observe the end point. viologen indigotrisulfonic acid 5,6-dimethylphenanthroline (Fe complex) phenosafranine Which color change would you observe at the end point? red to colorless red to yellow-green yellow-green to red blue to colorless

Fundamentals Of Analytical Chemistry
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Chapter21: Potentiometry
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Problem 21.26QAP
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A solution of Cu* is undergoing a redox titration by the addition of Ce*. The standard reduction half-reactions and potentials
are given.
Ce* +e= Ce*
E = +1.72 V
Cu+ + e Cu
E = +0.161 V
The table shows the properties of four redox indicators.
Color
Indicator
Oxidized
Reduced E" (V)
5,6-dimethylphenanthroline (Fe complex)
indigotrisulfonic acid
yellow-green
red
+0.97
blue
colorless
+0.33
phenosafranine
red
colorless
+0.28
viologen
colorless
blue
-0.43
Select a suitable indicator to observe the end point.
viologen
indigotrisulfonic acid
5,6-dimethylphenanthroline (Fe complex)
phenosafranine
Which color change would you observe at the end point?
red to colorless
red to yellow-green
yellow-green to red
blue to colorless
colorless to blue
colorless to red
Transcribed Image Text:A solution of Cu* is undergoing a redox titration by the addition of Ce*. The standard reduction half-reactions and potentials are given. Ce* +e= Ce* E = +1.72 V Cu+ + e Cu E = +0.161 V The table shows the properties of four redox indicators. Color Indicator Oxidized Reduced E" (V) 5,6-dimethylphenanthroline (Fe complex) indigotrisulfonic acid yellow-green red +0.97 blue colorless +0.33 phenosafranine red colorless +0.28 viologen colorless blue -0.43 Select a suitable indicator to observe the end point. viologen indigotrisulfonic acid 5,6-dimethylphenanthroline (Fe complex) phenosafranine Which color change would you observe at the end point? red to colorless red to yellow-green yellow-green to red blue to colorless colorless to blue colorless to red
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