A student proposed the following mechanism for the gas phase reaction of fluorine with chlorine dioxide. step 1 fast: 2 CIO2 Cl204 step 2 slow: Cl204 + F2 → 2 FCIO2 (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. + (2) Enter the formula of any species that acts as a reaction intermediate? If none leave box blank: (3) Complete the rate law for the overall reaction that is consistent with this mechanism. Use the form k[A]m[B]^... , where '1' is understood (so don't write it if it's a '1') for m, n etc. Rate =

Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.63PAE: The following mechanism is proposed for a reaction: NO + Br2 —* NOBr2 (slow) NOBr2 + NO —»2 NOBr...
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A student proposed the following mechanism for the gas phase reaction of fluorine with chlorine dioxide.
step 1
fast:
2 CIO2
Cl204
step 2
slow:
Cl204 + F2
→ 2 FCIO2
(1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not
needed, leave it blank.
+
+
(2) Enter the formula of any species that acts as a reaction intermediate? If none leave box
blank:
(3) Complete the rate law for the overall reaction that is consistent with this mechanism.
Use the form k[A]m[B]"... , where '1' is understood (so don't write it if it's a '1') for m, n etc.
Rate =
Transcribed Image Text:A student proposed the following mechanism for the gas phase reaction of fluorine with chlorine dioxide. step 1 fast: 2 CIO2 Cl204 step 2 slow: Cl204 + F2 → 2 FCIO2 (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. + + (2) Enter the formula of any species that acts as a reaction intermediate? If none leave box blank: (3) Complete the rate law for the overall reaction that is consistent with this mechanism. Use the form k[A]m[B]"... , where '1' is understood (so don't write it if it's a '1') for m, n etc. Rate =
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