(a) The unit cells of three structural types of ionic! appear light and the cations dark). The anions occupy the lattice positions. (A) (B) (1) Name the common structural type for (A), (B) and (C). (Hint: a typical structural type is rutile (TiO₂).] (C) (ii) The structures (A), (B) and (C) can be considered as packing of anions with the cations occupying specific types of hole. For each structure: • ● state the unit cell that the packing of anions is based on. state which holes are occupied by the cations and what fraction of them are occupied. State the coordination numbers of the cations and anions for (A), (B) and (C).

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(a) The unit cells of three structural types of ionic solids are shown below (the anions
appear light and the cations dark). The anions occupy the lattice positions.
X
(B)
(A)
(i) Name the common structural type for (A), (B) and (C).
(Hint: a typical structural type is rutile (T1O₂).]
(C)
(ii) The structures (A), (B) and (C) can be considered as packing of anlons with the
cations occupying specific types of hole.
For each structure:
state the unit cell that the packing of anions is based on.
state which holes are occupied by the cations and what fraction of
them are occupied.
State the coordination numbers of the cations and anions for (A), (B) and (C).
Transcribed Image Text:(a) The unit cells of three structural types of ionic solids are shown below (the anions appear light and the cations dark). The anions occupy the lattice positions. X (B) (A) (i) Name the common structural type for (A), (B) and (C). (Hint: a typical structural type is rutile (T1O₂).] (C) (ii) The structures (A), (B) and (C) can be considered as packing of anlons with the cations occupying specific types of hole. For each structure: state the unit cell that the packing of anions is based on. state which holes are occupied by the cations and what fraction of them are occupied. State the coordination numbers of the cations and anions for (A), (B) and (C).
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