A unimolecular reaction is observed to have the following rate constants at the indicated temperature. Determine the activation energy [E] and ΔH‡ [H] at 25ºC.   k at 0ºC = 2.46 × 10–3 /sec k at 20ºC = 4.51 × 10–2 /sec k at 100ºC = 5.76 × 10–1 /sec

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Chapter12: Chemical Kinetics
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A unimolecular reaction is observed to have the following rate constants at the indicated temperature. Determine the activation energy [E] and ΔH [H] at 25ºC.

 

k at 0ºC = 2.46 × 10–3 /sec

k at 20ºC = 4.51 × 10–2 /sec

k at 100ºC = 5.76 × 10–1 /sec

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