Answered: A voltaic cell utilizes the following…

Chemistry & Chemical Reactivity

10th Edition

ISBN:9781337399074

Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Chapter19: Principles Of Chemical Reactivity: Electron Transfer Reactions

Section19.5: Electrochemical Cells Under Nonstandard Conditions

Problem 19.7CYU: The half-cells Ag+(aq. 1.0 M)|Ag(s) and H+(aq, ? M)|H2(1.0 bar) are linked by a salt bridge to...

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Question

A voltaic cell utilizes the following reaction:
Al(s) + 3 Ag⁺(aq)--->Al³⁺(aq) + 3 Ag(s)
What is the effect on the cell emf of each of the following
changes? (a) Water is added to the anode half-cell, diluting
the solution. (b) The size of the aluminum electrode is
increased. (c) A solution of AgNO₃ is added to the cathode
half-cell, increasing the quantity of Ag+ but not changing
its concentration. (d) HCl is added to the AgNO₃ solution,
precipitating some of the Ag+ as AgCl.

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