A wastewater treatment plant discharges 10 MGD effluent containing 200 mg/L ultimate BOD into a stream flowing at 90 MGD with ultimate BOD of 5 mg/L. The deoxygenation constant, kd, is 0.12/day. (a) What is the ultimate BOD (BOD) remaining in the stream at a distance of 10,000 m downstream if the stream flows at a constant speed of 0.10 m/s?
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- An aqueous waste stream that has a maximum concentrationof 0.50 M H₂SO₄ (d=1.030 g/mL at 25C) will be neutralized by controlled addition of 40% caustic soda (NaOH; d=1.430 g/L) before it goes to the process sewer and then to the chemical plant waste treatment facility. However, a safety re-view finds that the waste stream could meet a small stream of animmiscible organic compound, which could form a flammable vapor in air at 40.°C. The maximum temperature of the causticsoda and the waste stream is 31°C. Could the temperature in-crease due to the heat of neutralization cause the vapor to ex-plode? Assume the specific heat capacity of each solution is 4.184 J/gK.An excess amount of Ba(NO3)2 was added to 2 liters of water at 25 oC until the solution is saturated. Because Ba(NO3)2 is only slightly soluble in water, the excess Ba(NO3)2 was filtered out to get a solid-free mixture. The proponents of the experiment thought about using the concept of colligative properties, specifically boiling point elevation, to determine Ksp. It was observed in their experiments that the solution boils at 100.15 deg C. Kb of water = 0.51 K-kg/mol. Barium nitrate dissociates using: Solve the ff: a) Amount of Ba(NO3)2 dissolved in grams. MW of Ba(NO3)2 = 261.3 g/molb) Solubility product, Kspc) Vapor pressure of the solution in kPaA solution of 0.50g of an unknown nonvolatile, nonelectrolyte solute is added to 100 mL of water at 298 K and then placed across a semipermeable embrane from a volume of pure water. When the system reaches equillibrium, the solution compartment is elevated 5.6 cm above the solvent compartment. Assuming that the density of the solution is 1.0 g/mL, calculate the molar mass of the unknown.
- Maple water is concentrated using the reverse osmosis process. What pressure (in kPa) must be imposed to obtain maple water with a mass percentage of 21.10%m/m and a density of 1.088 g/mL?The temperature is then 24.35 °C Note: sucrose is not an electrolyte and it is assumed that maple water consists only of sucrose and water. The molar mass of sucrose is 342.30 g/mol. Note: The density of pure water is 1.000 g/mL.R = 8.3145 kPa-L-mol-1-K-10 K = -273.15 °CElectrolytic manganese dioxide can be prepared from manganese carbonate ore by crushing,milling and leaching the ore in sulphuric acid. Manganese sulphate is crystallised from thesolution, redissolved and electrolysed to give the manganese dioxide.If the crystallisation were performed in a 30m3 tank and the concentration of the solutionentering the tank were 160 grams per litre and left the tank at 40 grams per litre, how muchMnSO4.5H2O would be produced.What is meant by Centrifugation and How to calculate a desire RCF and rpm for the separation of mixture of liquids?
- Calculate the solubility at 25°C of PbCO3 in pure water and in a 0.0110M PbNO32 solution. You'll find Ksp data in the ALEKS Data tab. Round both of your answers to 2 significant digits. solubility in pure water: gL solubility in 0.0110 M Pb(NO3)2solution: gLThe following evidence was obtained from an experiment to determine the solubility of calcium chloride at room temperature. A sample of saturated calcium chloride solution was evaporated to dryness, and the mass of solid residue was measured.EvidenceVolume of solution (mL) = 15.0Mass of empty beaker (g) = 90.54Mass of beaker and residue (g) = 101.36The solubility of calcium chloride is g/100 mLthe dimensionless Henry's law constant for trichloroethylene at 25 degrees Celcius is 0.4. A sealed glass vial is prepared that has an air volume of 4ml overlying an aqueous volume of 36ml. TCE is added to the aqueous phase so that initially it has an aqueous-phase concentration of 100 ppb. After the system equilibrates, what will be the concentration (in units of microgram per liter) of TCE in the aqueous phase
- A 0.512 g sample of a commercial phosphate detergent was ignited at a red heat to destroy the organic matter. The residue was taken up in hot HCl, which converted the P to H3PO4. The phosphate was precipitated as MgNH4PO4.6H2O by addition of Mg2+ followed by aqueous NH3. After being filtered and washed the precipitate was converted to Mg2P2O7 by ignition at 1000 0C and the residue weighed 0.1151g. (a) What is the Gravimetric Factor to convert Mg2P2O7 to P? (b) Calculate the percent P in the sample could you type it out pleaseIn an experiment to calculate the solubility product (Ksp) of barium nitrate (Ba(NO3)2), an excess amount of Ba(NO3)2 was added to 2 liters of water at 25oC until the solution is saturated. Because Ba(NO3)2 is only slightly soluble in water, the excess Ba(NO3)2 was filtered out to get a solid-free mixture. The proponents of the experiment thought about using the concept of colligative properties, specifically boiling point elevation, to determine Ksp. It was observed in their experiments that the solution boils at 100.15 K. Barium nitrate dissociates via the process: Ba(NO3)2(s) ⇄ Ba2+(aq) + 2NO?-3(?q) Ksp = [Ba2+][NO3−]2 Calculate the following if Kb,water = 0.51 K-kg/mol: a) Amount of Ba(NO3)2 dissolved in grams. Molar mass of Ba(NO3)2 = 261.3 g/mol b) Solubility product, Ksp c) Vapor pressure of the solution in kPaIn an experiment to calculate the solubility product (Ksp) of barium nitrate (Ba(NO3)2), an excess amount of Ba(NO3)2 was added to 2 liters of water at 25oC until the solution is saturated. Because Ba(NO3)2 is only slightly soluble in water, the excess Ba(NO3)2 was filtered out to get a solid-free mixture. The proponents of the experiment thought about using the concept of colligative properties, specifically boiling point elevation, to determine Ksp. It was observed in their experiments that the solution boils at 100.15 K. Barium nitrate dissociates via the process: ?a(??3)2(?) ⇄ ??2+(?q) + 2??-3(?q) ??p = [??2+][??3−]2 Calculate the following if Kb,water = 0.51 K-kg/mol: a) Amount of Ba(NO3)2 dissolved in grams. Molar mass of Ba(NO3)2 = 261.3 g/mol b) Solubility product, Ksp c) Vapor pressure of the solution in kPa