Consider the three structures. 1,1-dimethylcyclobutane (a) Which of these structures has the most angle strain? staggered butane 1,1,3,3,5,5-hexamethylcyclohexane 1,1,3,3,5,5-hexamethylcyclohexane 1,1-dimethylcyclobutane (c) Which of these structures has the most torsional (eclipsing) strain? staggered butane 1,1-dimethylcyclobutane 1,1,3,3,5,5-hexamethylcyclohexane staggered butane H HI H3C H CH3 (b) Which of these structures has the most steric strain? 1,1-dimethylcyclobutane staggered butane 1,1,3,3,5,5-hexamethylcyclohexane

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter2: Alkanes And Cycloalkanes
Section: Chapter Questions
Problem 2.49P: Use your answers from Problem 2.48 to complete the table showing correlations between cis,trans and...
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Question 5 of 7
O Macmillan Learning
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Consider the three structures.
1,1-dimethylcyclobutane
1,1,3,3,5,5-hexamethylcyclohexane
#
(a) Which of these structures has the most angle strain?
staggered butane
O 1,1,3,3,5,5-hexamethylcyclohexane
O 1,1-dimethylcyclobutane
(c) Which of these structures has the most torsional
(eclipsing) strain?
staggered butane
O 1,1-dimethylcyclobutane
O 1,1,3,3,5,5-hexamethylcyclohexane
staggered butane
H
H
2
H
H₂C
CH3
(b) Which of these structures has the most steric strain?
1,1,3,3,5,5-hexamethylcyclohexane
1,1-dimethylcyclobutane
staggered butane
Transcribed Image Text:Question 5 of 7 O Macmillan Learning > Consider the three structures. 1,1-dimethylcyclobutane 1,1,3,3,5,5-hexamethylcyclohexane # (a) Which of these structures has the most angle strain? staggered butane O 1,1,3,3,5,5-hexamethylcyclohexane O 1,1-dimethylcyclobutane (c) Which of these structures has the most torsional (eclipsing) strain? staggered butane O 1,1-dimethylcyclobutane O 1,1,3,3,5,5-hexamethylcyclohexane staggered butane H H 2 H H₂C CH3 (b) Which of these structures has the most steric strain? 1,1,3,3,5,5-hexamethylcyclohexane 1,1-dimethylcyclobutane staggered butane
Question 6 of 7
The images illustrate isomers of 1,2-di(2-methylpropyl)cyclohexane in conformational structures. Two are cis and two are trans.
Indicate which is the more stable conformation for the cis and which for the trans, and indicate which of all the conformations is
the most stable.
O Macmillan Learning
H
H
H
H
H
#
-H
H
H
H
A
H
H
A
B
D
H
Н
H
H
H
H
B
H
THE THE
D
H
H
For each question, if both conformations of the isomer are equally stable, select both.
Select the more stable conformation of cis-1,2-di(2-methylpropyl)cyclohexan
Transcribed Image Text:Question 6 of 7 The images illustrate isomers of 1,2-di(2-methylpropyl)cyclohexane in conformational structures. Two are cis and two are trans. Indicate which is the more stable conformation for the cis and which for the trans, and indicate which of all the conformations is the most stable. O Macmillan Learning H H H H H # -H H H H A H H A B D H Н H H H H B H THE THE D H H For each question, if both conformations of the isomer are equally stable, select both. Select the more stable conformation of cis-1,2-di(2-methylpropyl)cyclohexan
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