a. C3H0O2 b. EtO OEt diethyl maleate C3H1802

Chemistry: Matter and Change
1st Edition
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Chapter23: The Chemistry Of Life
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Many variations of ring-closing metathesis have now been reported. Tandem ring–opening–ring-closing metathesis can occur with cyclic alkenes that contain two additional carbon–carbon double bonds. In this reaction, the cycloalkene is cleaved, and two new rings are formed. [1] What compounds are formed in this tandem reaction with the following substrates? [2] Devise a synthesis of the substrate in part (b) that uses a Diels–Alder reaction with diethyl maleate as the dienophile.

a.
C3H0O2
b.
EtO
OEt
diethyl maleate
C3H1802
Transcribed Image Text:a. C3H0O2 b. EtO OEt diethyl maleate C3H1802
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