A. Freezing Point of Cyclohexane (Solvent) 1. Mass of beaker, test tube (g) 85.364g 2. Freezing point, from cooling curve (°C) 5.68°C B. Freezing Point of Cyclohexane plus Unknown Solute 1. Mass of beaker, test tube, cyclohexane (g) 97.594g 2.* Mass of cyclohexane (g) 3. Tared mass of added solute (g) 0.311g 4. Freezing point, from cooling curve (°C) 1.72°C Calculations 1. ke for cyclohexane (°Ckg/mol) 20.0°C-kg/mol 2. Freezing-point change AT:(°C) 3. Mass of cyclohexane in solution (kg) 4. Moles of solute, total (mol) 5. Mass of solute, total (g) 6. Molar mass of solute (g/mol) Based on your data (the molar of your unknown) what is the likely identity of the solute from the following selection: Naphthalene [C10Hg=128.171g/mol] Aspirin [C,H3O=180.158g/mol] Sucrose [C12H2201=342.3g/mol] Pentanoic acid [C;H19O2=102.13g/mol] 1-Pentanol [C§H120=88.15g/mol] Lactic acid [C3H03=90.08g/mol] 7. Identity of your unknown. Key Equations: ATu: change in the freezing point (°C) n: moles of solute m: molality Uolven' mass of solvent (kg) Molmai Molar of mass of solute ke freezing point depression of solvent i: Van't Hoff factor Uowwi mass of solute (g) ATK = i k,m m=n/mobouh AT = i kelowa/ Mi ATK =| Toow - Tuvw

Chemistry & Chemical Reactivity
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Chapter13: Solutions And Their Behavior
Section: Chapter Questions
Problem 106SCQ
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A. Freezing Point of Cyclohexane (Solvent)
1. Mass of beaker, test tube (g)
85.364g
2. Freezing point, from cooling curve (°C)
5.68°C
B. Freezing Point of Cyclohexane plus Unknown Solute
1. Mass of beaker, test tube, cyclohexane (g)
97.594g
2.* Mass of cyclohexane (g)
3. Tared mass of added solute (g)
0.311g
4. Freezing point, from cooling curve (°C)
1.72°C
Calculations
1. ke for cyclohexane (°Ckg/mol)
20.0°C-kg/mol
2. Freezing-point change AT:(°C)
3. Mass of cyclohexane in solution (kg)
4. Moles of solute, total (mol)
5. Mass of solute, total (g)
6. Molar mass of solute (g/mol)
Based on your data (the molar of your unknown) what is the likely identity of the solute from the following
selection:
Naphthalene [C1oHs=128.171g/mol]
Aspirin [C,HgO=180.158g/mol]
Sucrose [C12H2201-342.3g/mol]
Pentanoic acid [C;H1,Oz=102.13g/mol]
1-Pentanol [C3H12O=88.15g/mol]
Lactic acid [C3H603=90.08g/mol]
7. Identity of your unknown.
Key Equations:
AT: change in the freezing point (°C)
n: moles of solute
m: molality
Molvent mass of solvent (kg)
Meolme; Molar of mass of solute
ke freezing point depression of solvent
i: Van't Hoff factor
Moolutei mass of solute (g)
AT =i k,m
m= n/mobonk
AT =i keloval e Mi
ATu =| Toos - Tinitia |
Transcribed Image Text:A. Freezing Point of Cyclohexane (Solvent) 1. Mass of beaker, test tube (g) 85.364g 2. Freezing point, from cooling curve (°C) 5.68°C B. Freezing Point of Cyclohexane plus Unknown Solute 1. Mass of beaker, test tube, cyclohexane (g) 97.594g 2.* Mass of cyclohexane (g) 3. Tared mass of added solute (g) 0.311g 4. Freezing point, from cooling curve (°C) 1.72°C Calculations 1. ke for cyclohexane (°Ckg/mol) 20.0°C-kg/mol 2. Freezing-point change AT:(°C) 3. Mass of cyclohexane in solution (kg) 4. Moles of solute, total (mol) 5. Mass of solute, total (g) 6. Molar mass of solute (g/mol) Based on your data (the molar of your unknown) what is the likely identity of the solute from the following selection: Naphthalene [C1oHs=128.171g/mol] Aspirin [C,HgO=180.158g/mol] Sucrose [C12H2201-342.3g/mol] Pentanoic acid [C;H1,Oz=102.13g/mol] 1-Pentanol [C3H12O=88.15g/mol] Lactic acid [C3H603=90.08g/mol] 7. Identity of your unknown. Key Equations: AT: change in the freezing point (°C) n: moles of solute m: molality Molvent mass of solvent (kg) Meolme; Molar of mass of solute ke freezing point depression of solvent i: Van't Hoff factor Moolutei mass of solute (g) AT =i k,m m= n/mobonk AT =i keloval e Mi ATu =| Toos - Tinitia |
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