a. Which has highest lattice energy-NaF or CaO? Given that the internuclear distance between the ions in NaF is 231 pm and that between the ions in CaO is 239 pm. Explain your reasoning b. Which has the highest melting point? Explain your reasoning.

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter12: Solutions
Section: Chapter Questions
Problem 12.4QE
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Predicting the solubility of ionic compounds
a. Which has highest lattice energy- NaF or CaO? Given that the internuclear distance between
the ions in NaF is 231 pm and that between the ions in CaO is 239 pm. Explain your reasoning
b. Which has the highest melting point? Explain your reasoning.
c. Which compound(s) would you predict would be soluble in water? Explain your reasoning!
d. In general, can you predict which ionic compounds are soluble in water and which ones are
insoluble in water?
e. Effect of temperature on solubility of salts (ionic compounds). What trend can you see from
the graph shown below?
Salt Solubities with Temperature
Explain this trend in
thermodynamic terms?
How does increasing the
temp affect AH, AS and
150
140
NaCi
130
KNO3
120
NANO3
KCIO3
110
KCI
100
KI
AG?
NH4CI
70
60
40
30
20
10
10
20
30
40
50
60
70
90
100
"C (Celsius)
grams salt/100 g water
Transcribed Image Text:Predicting the solubility of ionic compounds a. Which has highest lattice energy- NaF or CaO? Given that the internuclear distance between the ions in NaF is 231 pm and that between the ions in CaO is 239 pm. Explain your reasoning b. Which has the highest melting point? Explain your reasoning. c. Which compound(s) would you predict would be soluble in water? Explain your reasoning! d. In general, can you predict which ionic compounds are soluble in water and which ones are insoluble in water? e. Effect of temperature on solubility of salts (ionic compounds). What trend can you see from the graph shown below? Salt Solubities with Temperature Explain this trend in thermodynamic terms? How does increasing the temp affect AH, AS and 150 140 NaCi 130 KNO3 120 NANO3 KCIO3 110 KCI 100 KI AG? NH4CI 70 60 40 30 20 10 10 20 30 40 50 60 70 90 100 "C (Celsius) grams salt/100 g water
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