Acetone is brominated in acidic solution according to the following reaction: CH3COCH3(aq) + Br₂(aq) → CH₂COCH₂Br(aq) + H*(aq) + Br(aq) What is the rate law implied by the mechanism given below? CH3COCH3(aq) + H+ (aq) → CH3C(OH)CH₂ (aq) reversible) CH3C(OH)CH₂+(aq) → CH3C(OH)=CH₂(aq) + H+(aq) CH3C(OH)=CH₂(aq) CH3C(OH)CH₂Br*(aq) + Br₂(aq)→ CH₂C(OH)CH₂Br*(aq) + Br(aq) → CH3COCH₂Br(aq) + H¯(aq) (slow) (fast) (fast, (fast)
Acetone is brominated in acidic solution according to the following reaction: CH3COCH3(aq) + Br₂(aq) → CH₂COCH₂Br(aq) + H*(aq) + Br(aq) What is the rate law implied by the mechanism given below? CH3COCH3(aq) + H+ (aq) → CH3C(OH)CH₂ (aq) reversible) CH3C(OH)CH₂+(aq) → CH3C(OH)=CH₂(aq) + H+(aq) CH3C(OH)=CH₂(aq) CH3C(OH)CH₂Br*(aq) + Br₂(aq)→ CH₂C(OH)CH₂Br*(aq) + Br(aq) → CH3COCH₂Br(aq) + H¯(aq) (slow) (fast) (fast, (fast)
General Chemistry - Standalone book (MindTap Course List)
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Chapter13: Rates Of Reaction
Section: Chapter Questions
Problem 13.51QP: In experiments on the decomposition of azomethane. CH3NHCH3(g)C2H6(g)+N2(g) the following data were...
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![15. Acetone is brominated in acidic solution according to the following reaction:
CH3COCH3(aq) + Br₂(aq) → CH₂COCH₂Br(aq) + H*(aq) + Br(aq)
What is the rate law implied by the mechanism given below?
CH3COCH3(aq) + H*(aq) ⇒ CH3C(OH)CH3*(aq)
reversible)
CH3C(OH)CH3 + (aq) → CH3C(OH)=CH₂(aq) + H+(aq)
(slow)
CH3C(OH)=CH₂(aq) + Br₂(aq)⇒ CH₂C(OH)CH₂Br¯(aq) + Br(aq)
CH3C(OH)CH₂Br*(aq) → CH3COCH₂Br(aq) + H*(aq)
(fast)
A) Rate = K[CH3COCH3][H]
B) Rate = k[CH3COCH3]
C) Rate = k[CH3COCH3][Br₂]
Rate = k[CH3COCH3]²
D)
E) Rate = k[CH3COCH₂3][Br₂]/[H*]
(fast,
(fast)](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F3df76355-c35e-410c-9675-4007e75a2553%2F51a34f68-af68-4656-86af-e38e770016d6%2Fq9cbvu5_processed.png&w=3840&q=75)
Transcribed Image Text:15. Acetone is brominated in acidic solution according to the following reaction:
CH3COCH3(aq) + Br₂(aq) → CH₂COCH₂Br(aq) + H*(aq) + Br(aq)
What is the rate law implied by the mechanism given below?
CH3COCH3(aq) + H*(aq) ⇒ CH3C(OH)CH3*(aq)
reversible)
CH3C(OH)CH3 + (aq) → CH3C(OH)=CH₂(aq) + H+(aq)
(slow)
CH3C(OH)=CH₂(aq) + Br₂(aq)⇒ CH₂C(OH)CH₂Br¯(aq) + Br(aq)
CH3C(OH)CH₂Br*(aq) → CH3COCH₂Br(aq) + H*(aq)
(fast)
A) Rate = K[CH3COCH3][H]
B) Rate = k[CH3COCH3]
C) Rate = k[CH3COCH3][Br₂]
Rate = k[CH3COCH3]²
D)
E) Rate = k[CH3COCH₂3][Br₂]/[H*]
(fast,
(fast)
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